Determination of the surface functionality of nanocarbon allotropes by boehm titration

Critical point (CP) in a titration curve to quantify carboxylic, lactonic, and phenolic groups on multi-walled carbon nanotube (CNT) and Vulcan carbon (VC). Titration technique used was Boehm type and tipping point measurement from titration curve was done by second derivative method. The calculatio...

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Detalles Bibliográficos
Autores: Hernández Ortíz, Marlen, Durán Muñóz, Héctor, Lozano López, J. D., Durón Torres, Sergio Miguel, Galván Valencia, Marisol, Estevez Martínez, Yoxkin, Ortíz Medina, Imelda, Ramírez Hernández, Leticia, Cruz Dominguez, Oscar, Castaño, Víctor
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:México
Institución:Universidad Autónoma de Zacatecas
Repositorio:Repositorio Institucional Caxcán
Idioma:español
OAI Identifier:oai:http://ricaxcan.uaz.edu.mx:20.500.11845/2543
Acceso en línea:http://ricaxcan.uaz.edu.mx/jspui/handle/20.500.11845/2543
Access Level:acceso abierto
Palabra clave:BIOLOGIA Y QUIMICA [2]
Surface functionality
nanocarbons
Boehm titration
Descripción
Sumario:Critical point (CP) in a titration curve to quantify carboxylic, lactonic, and phenolic groups on multi-walled carbon nanotube (CNT) and Vulcan carbon (VC). Titration technique used was Boehm type and tipping point measurement from titration curve was done by second derivative method. The calculation functional groups on nanocarbons (NCs) presents lowest uncertainty previously published. An order of ±10−4meq/g is the precision of the values obtained, one order of magnitude below reported. Both NCs display a high quantity of carboxylic groups created after being treated with regard to the other functional groups generated, mainly for functionalized Vulcan carbon VC-F.