Synthesis of Fluorescent oligo(p-phenyleneethynylene) (OPE3) via Sonogashira Reactions

Sonogashira reactions of 4-(2,5-diiodobenzoyl)morpholine and 4-(5-bromo-2-iodobenzoyl)morpholine with arylacetylenes catalyzed by Pd2(dba)3 in DMSO allowed preparation of fluorescent oligo( p-phenyleneethynylene)s (OPE3) with fluorescence quantum yields up to 0.87. DMSO proved to be very efficient f...

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Bibliographic Details
Authors: Mariana Flores-Jarillo, Francisco Ayala-Mata, Gerardo Zepeda-Vallejo, Rosa Ángeles Vázquez-García, Gabriel Ramos-Ortiz, Miguel Ángel Méndez-Rojas, Oscar Rodolfo Suárez-Castillo, Alejandro Alvarez-Hernández
Format: article
Status:Published version
Publication Date:2015
Country:México
Institution:Universidad de las Américas Puebla
Repository:Redalyc-UDLAP
OAI Identifier:oai:redalyc.org:47542144010
Online Access:https://www.redalyc.org/articulo.oa?id=47542144010
Access Level:Open access
Keyword:Química
OPE3
oligo(p
fluorescence
Sonogashira coupling
phenyleneethynylene)s
Description
Summary:Sonogashira reactions of 4-(2,5-diiodobenzoyl)morpholine and 4-(5-bromo-2-iodobenzoyl)morpholine with arylacetylenes catalyzed by Pd2(dba)3 in DMSO allowed preparation of fluorescent oligo( p-phenyleneethynylene)s (OPE3) with fluorescence quantum yields up to 0.87. DMSO proved to be very efficient for this double Sonogashira coupling in which other solvents failed.

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