Photoconductivity studies on amorphous and crystalline TiO2 films doped with gold nanoparticles

In this work, amorphous and crystalline TiO2 films were synthesized by the sol–gel process at room temperature. The TiO2 films were doped with gold nanoparticles. The films were spin-coated on glass wafers. The crystalline samples were annealed at 100°C for 30 minutes and sintered at 520°C for 2 h....

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Detalles Bibliográficos
Autores: Valverde Aguilar, Guadalupe, García Macedo, Jorge, Rentería Tapia, Victor, Aguilar Franco, Manuel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2011
País:México
Institución:Instituto Politécnico Nacional
Repositorio:Repositorio Digital del IPN
OAI Identifier:oai:www.repositoriodigital.ipn.mx:123456789/10680
Acceso en línea:http://hdl.handle.net/123456789/162
http://www.repositoriodigital.ipn.mx/handle/123456789/10680
Access Level:acceso abierto
Palabra clave:Gold nanoparticles
Gans theory
Descripción
Sumario:In this work, amorphous and crystalline TiO2 films were synthesized by the sol–gel process at room temperature. The TiO2 films were doped with gold nanoparticles. The films were spin-coated on glass wafers. The crystalline samples were annealed at 100°C for 30 minutes and sintered at 520°C for 2 h. All films were characterized using X-ray diffraction, transmission electronic microscopy and UV-Vis absorption spectroscopy. Two crystalline phases, anatase and rutile, were formed in the matrix TiO2 and TiO2/Au. An absorption peak was located at 570 nm (amorphous) and 645 nm (anatase). Photoconductivity studies were performed on these films. The experimental data were fitted with straight lines at darkness and under illumination at 515 nm and 645 nm. This indicates an ohmic behavior. Crystalline TiO2/Au films are more photoconductive than the amorphous ones.