Review and perspective: Next generation DME synthesis technologies for the energy transition

Renewable dimethyl ether (DME) is expected to contribute to the decarbonization of several sectors, including domestic heat supply and transport. The shift of the carbon source used for the production of DME from fossil to renewable, such as biomass, waste or captured CO2, entails an industrial chal...

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Autores: Peinado Cebrián, Cristina, Liuzzi, Dalia, Sluijter, Soraya N., Skorikova, Galina, Boon, Jurriaan, Guffanti, Simone, Groppi, Gianpiero, Rojas Muñoz, Sergio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/389495
Acceso en línea:http://hdl.handle.net/10261/389495
https://api.elsevier.com/content/abstract/scopus_id/85178380214
Access Level:acceso abierto
Palabra clave:Catalysts
DME
Kinetics
Sorption Enhanced DME Synthesis (SEDMES)
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spelling Review and perspective: Next generation DME synthesis technologies for the energy transitionPeinado Cebrián, CristinaLiuzzi, DaliaSluijter, Soraya N.Skorikova, GalinaBoon, JurriaanGuffanti, SimoneGroppi, GianpieroRojas Muñoz, SergioCatalystsDMEKineticsSorption Enhanced DME Synthesis (SEDMES)Renewable dimethyl ether (DME) is expected to contribute to the decarbonization of several sectors, including domestic heat supply and transport. The shift of the carbon source used for the production of DME from fossil to renewable, such as biomass, waste or captured CO2, entails an industrial challenge in terms of reactors, operation regimes, catalysts and product purification, with strong technical and economic repercussions. In this work, we review the latest developments on this topic, focusing on the direct synthesis of DME, and especial attention has been paid to the separation-enhanced technologies for DME production, including the Sorption Enhanced DME Synthesis (SEDMES). We address other aspects that are often neglected, such as the impact of heat and mass transfer phenomena, which become increasingly relevant in processes in which several reaction and sorption stages occur in the same reactor. We also include a techno-economic section that gives insight in the feasibility of several renewable DME production processes. Finally, we review the most recently deployed installations for renewable DME production, at commercial or pilot scale, as a model of the near-future of the DME industry.This research was supported by MCIN with funding from NextGenerationEU (PRTR-C17.I1) within the Planes Complementarios con CCAA (Area of Green Hydrogen and Energy) and it has been carried out in the CSIC Interdisciplinary Thematic Platform (PTI+ ) Transición Energética Sostenible+ (PTI-TRANSENER+ ) CP acknowledges funds from Programa Garantía Juvenil 2016 from CAM (PEJD‐2016/AMB‐2628). SNS, GS, and JB have received funding from Topsector Energie of the Ministry of Economic Affairs and Climate Policy of The Netherlands, under the project iDME (TIND 121006). We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI).Peer reviewedElsevier BVMinisterio de Ciencia e Innovación (España)European CommissionComunidad de MadridMinistry of Economic Affairs (The Netherlands)CSIC - Unidad de Recursos de Información Científica para la Investigación (URICI)Peinado Cebrián, Cristina [0000-0001-5072-3846]Liuzzi, Dalia [0000-0002-2754-3510]Rojas Muñoz, Sergio [0000-0002-1789-2848]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_dcae04bcPublisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/389495https://api.elsevier.com/content/abstract/scopus_id/85178380214reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#2016/AMB‐2628 PEJDThe underlying dataset has been published as supplementary material of the article in the publisher platform at DOI https://doi.org/10.1016/j.cej.2023.147494https://doi.org/10.1016/j.cej.2023.147494Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3894952026-05-22T06:33:51Z
dc.title.none.fl_str_mv Review and perspective: Next generation DME synthesis technologies for the energy transition
title Review and perspective: Next generation DME synthesis technologies for the energy transition
spellingShingle Review and perspective: Next generation DME synthesis technologies for the energy transition
Peinado Cebrián, Cristina
Catalysts
DME
Kinetics
Sorption Enhanced DME Synthesis (SEDMES)
title_short Review and perspective: Next generation DME synthesis technologies for the energy transition
title_full Review and perspective: Next generation DME synthesis technologies for the energy transition
title_fullStr Review and perspective: Next generation DME synthesis technologies for the energy transition
title_full_unstemmed Review and perspective: Next generation DME synthesis technologies for the energy transition
title_sort Review and perspective: Next generation DME synthesis technologies for the energy transition
dc.creator.none.fl_str_mv Peinado Cebrián, Cristina
Liuzzi, Dalia
Sluijter, Soraya N.
Skorikova, Galina
Boon, Jurriaan
Guffanti, Simone
Groppi, Gianpiero
Rojas Muñoz, Sergio
author Peinado Cebrián, Cristina
author_facet Peinado Cebrián, Cristina
Liuzzi, Dalia
Sluijter, Soraya N.
Skorikova, Galina
Boon, Jurriaan
Guffanti, Simone
Groppi, Gianpiero
Rojas Muñoz, Sergio
author_role author
author2 Liuzzi, Dalia
Sluijter, Soraya N.
Skorikova, Galina
Boon, Jurriaan
Guffanti, Simone
Groppi, Gianpiero
Rojas Muñoz, Sergio
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
European Commission
Comunidad de Madrid
Ministry of Economic Affairs (The Netherlands)
CSIC - Unidad de Recursos de Información Científica para la Investigación (URICI)
Peinado Cebrián, Cristina [0000-0001-5072-3846]
Liuzzi, Dalia [0000-0002-2754-3510]
Rojas Muñoz, Sergio [0000-0002-1789-2848]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Catalysts
DME
Kinetics
Sorption Enhanced DME Synthesis (SEDMES)
topic Catalysts
DME
Kinetics
Sorption Enhanced DME Synthesis (SEDMES)
description Renewable dimethyl ether (DME) is expected to contribute to the decarbonization of several sectors, including domestic heat supply and transport. The shift of the carbon source used for the production of DME from fossil to renewable, such as biomass, waste or captured CO2, entails an industrial challenge in terms of reactors, operation regimes, catalysts and product purification, with strong technical and economic repercussions. In this work, we review the latest developments on this topic, focusing on the direct synthesis of DME, and especial attention has been paid to the separation-enhanced technologies for DME production, including the Sorption Enhanced DME Synthesis (SEDMES). We address other aspects that are often neglected, such as the impact of heat and mass transfer phenomena, which become increasingly relevant in processes in which several reaction and sorption stages occur in the same reactor. We also include a techno-economic section that gives insight in the feasibility of several renewable DME production processes. Finally, we review the most recently deployed installations for renewable DME production, at commercial or pilot scale, as a model of the near-future of the DME industry.
publishDate 2024
dc.date.none.fl_str_mv 2024
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_dcae04bc
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/389495
https://api.elsevier.com/content/abstract/scopus_id/85178380214
url http://hdl.handle.net/10261/389495
https://api.elsevier.com/content/abstract/scopus_id/85178380214
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
2016/AMB‐2628 PEJD
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI https://doi.org/10.1016/j.cej.2023.147494
https://doi.org/10.1016/j.cej.2023.147494
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier BV
publisher.none.fl_str_mv Elsevier BV
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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repository.mail.fl_str_mv
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