Storing energy with molecular photoisomers

Some molecular photoisomers can be isomerized to a metastable high-energy state by exposure to light. These molecules can then be thermally or catalytically converted back to their initial state, releasing heat in the process. Such a reversible photochemical process has been considered for developin...

ver descrição completa

Detalhes bibliográficos
Autores: Wang, Zhihang, Erhart, Paul, Li, Tao, Zhang, Zhao Yang, Sampedro, Diego, Hu, Zhiyu, Wegner, Hermann A., Brummel, Olaf, Libuda, Jörg, Nielsen, Mogens Brøndsted, Moth-Poulsen, Kasper
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/264449
Acesso em linha:http://hdl.handle.net/10261/264449
https://api.elsevier.com/content/abstract/scopus_id/85121012855
Access Level:acceso abierto
Palavra-chave:Energy storage
Photoisomers
Photoswitches
Solar energy
id ES_ffa8d29dd67b6ad715de364ea969c65a
oai_identifier_str oai:digital.csic.es:10261/264449
network_acronym_str ES
network_name_str España
repository_id_str
spelling Storing energy with molecular photoisomersWang, ZhihangErhart, PaulLi, TaoZhang, Zhao YangSampedro, DiegoHu, ZhiyuWegner, Hermann A.Brummel, OlafLibuda, JörgNielsen, Mogens BrøndstedMoth-Poulsen, KasperEnergy storagePhotoisomersPhotoswitchesSolar energySome molecular photoisomers can be isomerized to a metastable high-energy state by exposure to light. These molecules can then be thermally or catalytically converted back to their initial state, releasing heat in the process. Such a reversible photochemical process has been considered for developing molecular solar thermal (MOST) systems. In this review, we introduce the concept, criteria, and state-of-the-art of MOST systems, with an emphasis on the three most promising molecular systems: norbornadiene/quadricyclane, E/Z-azobenzene, and dihydroazulene/vinylheptafulvene. After discussing the fundamental working principles, we focus on molecular design strategies for improving solar energy storage performance, remaining challenges, and potential focus areas. Finally, we summarize the current molecular incorporation into functional devices and conclude with a perspective on challenges and future directions.Z.W. and K.M.-P. would like to thank the financial support from K. & A. Wallenberg foundation, the Swedish Foundation for Strategic Research, the Swedish research foundation FORMAS, and the European Union’s Horizon 2020 research and innovation program under grant agreement No. 951801. K.M.-P. acknowledges support from the Catalan Institution for Research and Advanced Studies. P.E. thanks the K. & A. Wallenberg foundation (2014.0226) and the Swedish Research Council (2020-04935). T.L. and Z.-Y.Z. thank the financial support from National Key Research and Development Program of China (2017YFA0207500), National Natural Science Foundation of China (22022507, 51973111), and Beijing National Laboratory for Molecular Sciences (BNLMS202004). D.S. thanks the financial support from MINECO/FEDER (CTQ2017-87372-P). O.B., J.L., and H.A.W. thank the Deutsche Forschungsgemeinschaft (DFG, project 392607742, 62201757). Additional support by the DFG is acknowledged through the Research Unit FOR 1878 “funCOS – Functional Molecular Structures on Complex Oxide Surfaces.” J.L. and O.B. acknowledge the cooperation with the groups of Julien Bachmann, Christian Papp, Andreas Hirsch, Andreas Görling, and Hans-Peter Steinrück in the framework of the studies described in this review. M.B.N. thanks the University of Copenhagen for financial support.With funding from the Spanish government through the ‘Severo Ochoa Centre of Excellence’ accreditation (CEX2019-000917-S).Peer reviewedCell PressKnut and Alice Wallenberg FoundationSwedish Foundation for Strategic ResearchSwedish Research Council for Sustainable DevelopmentEuropean CommissionGeneralitat de CatalunyaSwedish Research CouncilNational Key Research and Development Program (China)National Natural Science Foundation of ChinaBeijing National Laboratory for Molecular SciencesMinisterio de Economía y Competitividad (España)German Research FoundationUniversity of CopenhagenConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202220222021info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/264449https://api.elsevier.com/content/abstract/scopus_id/85121012855reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/951801info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-87372-Pinfo:eu-repo/grantAgreement/MICIU/Plan Estatal de investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-SJoulehttp://dx.doi.org/10.1016/j.joule.2021.11.001Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2644492026-05-22T06:33:51Z
dc.title.none.fl_str_mv Storing energy with molecular photoisomers
title Storing energy with molecular photoisomers
spellingShingle Storing energy with molecular photoisomers
Wang, Zhihang
Energy storage
Photoisomers
Photoswitches
Solar energy
title_short Storing energy with molecular photoisomers
title_full Storing energy with molecular photoisomers
title_fullStr Storing energy with molecular photoisomers
title_full_unstemmed Storing energy with molecular photoisomers
title_sort Storing energy with molecular photoisomers
dc.creator.none.fl_str_mv Wang, Zhihang
Erhart, Paul
Li, Tao
Zhang, Zhao Yang
Sampedro, Diego
Hu, Zhiyu
Wegner, Hermann A.
Brummel, Olaf
Libuda, Jörg
Nielsen, Mogens Brøndsted
Moth-Poulsen, Kasper
author Wang, Zhihang
author_facet Wang, Zhihang
Erhart, Paul
Li, Tao
Zhang, Zhao Yang
Sampedro, Diego
Hu, Zhiyu
Wegner, Hermann A.
Brummel, Olaf
Libuda, Jörg
Nielsen, Mogens Brøndsted
Moth-Poulsen, Kasper
author_role author
author2 Erhart, Paul
Li, Tao
Zhang, Zhao Yang
Sampedro, Diego
Hu, Zhiyu
Wegner, Hermann A.
Brummel, Olaf
Libuda, Jörg
Nielsen, Mogens Brøndsted
Moth-Poulsen, Kasper
author2_role author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Knut and Alice Wallenberg Foundation
Swedish Foundation for Strategic Research
Swedish Research Council for Sustainable Development
European Commission
Generalitat de Catalunya
Swedish Research Council
National Key Research and Development Program (China)
National Natural Science Foundation of China
Beijing National Laboratory for Molecular Sciences
Ministerio de Economía y Competitividad (España)
German Research Foundation
University of Copenhagen
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Energy storage
Photoisomers
Photoswitches
Solar energy
topic Energy storage
Photoisomers
Photoswitches
Solar energy
description Some molecular photoisomers can be isomerized to a metastable high-energy state by exposure to light. These molecules can then be thermally or catalytically converted back to their initial state, releasing heat in the process. Such a reversible photochemical process has been considered for developing molecular solar thermal (MOST) systems. In this review, we introduce the concept, criteria, and state-of-the-art of MOST systems, with an emphasis on the three most promising molecular systems: norbornadiene/quadricyclane, E/Z-azobenzene, and dihydroazulene/vinylheptafulvene. After discussing the fundamental working principles, we focus on molecular design strategies for improving solar energy storage performance, remaining challenges, and potential focus areas. Finally, we summarize the current molecular incorporation into functional devices and conclude with a perspective on challenges and future directions.
publishDate 2021
dc.date.none.fl_str_mv 2021
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/264449
https://api.elsevier.com/content/abstract/scopus_id/85121012855
url http://hdl.handle.net/10261/264449
https://api.elsevier.com/content/abstract/scopus_id/85121012855
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/H2020/951801
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-87372-P
info:eu-repo/grantAgreement/MICIU/Plan Estatal de investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-S
Joule
http://dx.doi.org/10.1016/j.joule.2021.11.001
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Cell Press
publisher.none.fl_str_mv Cell Press
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869425793902313472
score 15.811543

Registos relacionados