Enhanced magnetocaloric response in Cr/Mo containing Nanoperm-type amorphous alloys
The magnetocaloric effect of Fe76Cr8−xMoxCu1B15 (x =0,4) alloys is studied. Although the combined addition of Cr and Mo is more efficient in tuning the Curie temperature of the alloy, the Mo-free alloy presents a higher magnetocaloric response. The refrigerant capacity (RC) for the Mo-containing all...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2007 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/33293 |
| Acceso en línea: | http://hdl.handle.net/11441/33293 https://doi.org/10.1063/1.2437659 |
| Access Level: | acceso abierto |
| Palabra clave: | Chromium Entropy Molybdenum Refrigerants Refrigeration Thermal effects Curie temperature Magnetocaloric response Optimal refrigeration cycle Refrigerant capacity (RC) Amorphous alloys |
| Sumario: | The magnetocaloric effect of Fe76Cr8−xMoxCu1B15 (x =0,4) alloys is studied. Although the combined addition of Cr and Mo is more efficient in tuning the Curie temperature of the alloy, the Mo-free alloy presents a higher magnetocaloric response. The refrigerant capacity (RC) for the Mo-containing alloy is comparable to that of Gd5Ge1.9Si2Fe0.1 (for a field of 50 kOe, RC = 273 J kg−1 for the Mo alloy vs 240 J kg−1 for the Gd-based one), with a larger temperature span of the optimal refrigeration cycle (250 K vs 90 K, respectively). The restriction of the temperature span to 90 K gives RC = 187 J kg−1 for the Mo alloy. A master curve behavior for the magnetic entropy change is also evidenced. |
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