Corrosion inhibitor from nature: Fundamentals of tannic acid inhibition for AA2024 alloy

This study addresses the fundamentals of corrosion inhibition of AA2024 alloy by tannic acid (TA), a Cr-free and eco-friendly natural product. To this end, the AA2024 alloy was immersed in NaCl solution (50 mM) with different TA concentrations (0.1–10 mM) for 7 days. Surface (SEM, Raman, and SKPFM)...

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Detalles Bibliográficos
Autores: Del Olmo Martínez, Rubén, Bastos, Alexandre, Yasakau, Kiryl, Sushkova, Alesia, Arrabal Durán, Raúl, Tedim, João
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/118090
Acceso en línea:https://hdl.handle.net/20.500.14352/118090
Access Level:acceso abierto
Palabra clave:620
AA2024
Aluminium
Tannic acid
Corrosion inhibitor
Eco-friendly
Green inhibition
Materiales
3312 Tecnología de Materiales
Descripción
Sumario:This study addresses the fundamentals of corrosion inhibition of AA2024 alloy by tannic acid (TA), a Cr-free and eco-friendly natural product. To this end, the AA2024 alloy was immersed in NaCl solution (50 mM) with different TA concentrations (0.1–10 mM) for 7 days. Surface (SEM, Raman, and SKPFM) and electrochemical analyses (EIS, PDP, and SVET) revealed mixed inhibition after 1 day of immersion in TA solution. Long-term immersion tests in TA solutions produced a tannate-rich oxide film on the surface. The films with low tannate content (formed in 0.1 and 1 mM TA) showed the highest stability and corrosion resistance.