Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting

Cellulose nanocrystals (CNCs) are an emerging nanomaterial for applications ranging from coatings and construction to adhesives and biomedical devices. Owing to their high aspect ratio, stiffness, and reinforcing potential, CNCs have shown great promise to be used in polymer nanocomposites. However,...

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Detalles Bibliográficos
Autores: Kedzior, Stephanie, Zoppe, Justin Orazio|||0000-0002-3599-9227, Berry, Richard, Cranston, Emily
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/336265
Acceso en línea:https://hdl.handle.net/2117/336265
https://dx.doi.org/10.1016/j.cossms.2018.11.005
Access Level:acceso abierto
Palabra clave:Polymerization
Polymers
Nanocrystals
Cellulose
Nanostructured materials
Cellulose nanocrystals
Polymer grafting
Surface functionalization
Grafting to
Grafting from
Free radical polymerization
Ring opening polymerization
Controlled radical polymerization
Manufacturing considerations
Patents
Polimerització
Polímers
Nanocristalls
Cel·lulosa
Materials nanoestructurats
Àrees temàtiques de la UPC::Enginyeria dels materials
Àrees temàtiques de la UPC::Enginyeria química
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spelling Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer graftingKedzior, StephanieZoppe, Justin Orazio|||0000-0002-3599-9227Berry, RichardCranston, EmilyPolymerizationPolymersNanocrystalsCelluloseNanostructured materialsCellulose nanocrystalsPolymer graftingSurface functionalizationGrafting toGrafting fromFree radical polymerizationRing opening polymerizationControlled radical polymerizationManufacturing considerationsPatentsPolimeritzacióPolímersNanocristallsCel·lulosaMaterials nanoestructuratsÀrees temàtiques de la UPC::Enginyeria dels materialsÀrees temàtiques de la UPC::Enginyeria químicaCellulose nanocrystals (CNCs) are an emerging nanomaterial for applications ranging from coatings and construction to adhesives and biomedical devices. Owing to their high aspect ratio, stiffness, and reinforcing potential, CNCs have shown great promise to be used in polymer nanocomposites. However, due to their inherent hydrophilicity and compatibility with polar environments, the use of CNCs in hydrophobic polymer matrices or in organic solvent-based formulations has been limited. To overcome this incompatibility, many reports on grafting polymers onto the surface of CNCs have been published over the past ten years. This review describes the recent advances in CNC surface functionalization through polymer grafting, and comprehensively covers the existing work to date. Methods including polymer “grafting to” and “grafting from” are described in detail, using polymerization techniques such as free radical, ring opening, and controlled radical polymerization. Purification and characterization of polymer-grafted CNCs, the potential for upscaling these functionalization methods, and current perspectives from academic and industrial viewpoints are presentedPeer Reviewed20192019-04-0120212021-02-01journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/336265https://dx.doi.org/10.1016/j.cossms.2018.11.005reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivates 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/3362652026-05-27T15:37:01Z
dc.title.none.fl_str_mv Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
title Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
spellingShingle Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
Kedzior, Stephanie
Polymerization
Polymers
Nanocrystals
Cellulose
Nanostructured materials
Cellulose nanocrystals
Polymer grafting
Surface functionalization
Grafting to
Grafting from
Free radical polymerization
Ring opening polymerization
Controlled radical polymerization
Manufacturing considerations
Patents
Polimerització
Polímers
Nanocristalls
Cel·lulosa
Materials nanoestructurats
Àrees temàtiques de la UPC::Enginyeria dels materials
Àrees temàtiques de la UPC::Enginyeria química
title_short Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
title_full Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
title_fullStr Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
title_full_unstemmed Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
title_sort Recent advances and an industrial perspective of cellulose nanocrystal functionalization through polymer grafting
dc.creator.none.fl_str_mv Kedzior, Stephanie
Zoppe, Justin Orazio|||0000-0002-3599-9227
Berry, Richard
Cranston, Emily
author Kedzior, Stephanie
author_facet Kedzior, Stephanie
Zoppe, Justin Orazio|||0000-0002-3599-9227
Berry, Richard
Cranston, Emily
author_role author
author2 Zoppe, Justin Orazio|||0000-0002-3599-9227
Berry, Richard
Cranston, Emily
author2_role author
author
author
dc.subject.none.fl_str_mv Polymerization
Polymers
Nanocrystals
Cellulose
Nanostructured materials
Cellulose nanocrystals
Polymer grafting
Surface functionalization
Grafting to
Grafting from
Free radical polymerization
Ring opening polymerization
Controlled radical polymerization
Manufacturing considerations
Patents
Polimerització
Polímers
Nanocristalls
Cel·lulosa
Materials nanoestructurats
Àrees temàtiques de la UPC::Enginyeria dels materials
Àrees temàtiques de la UPC::Enginyeria química
topic Polymerization
Polymers
Nanocrystals
Cellulose
Nanostructured materials
Cellulose nanocrystals
Polymer grafting
Surface functionalization
Grafting to
Grafting from
Free radical polymerization
Ring opening polymerization
Controlled radical polymerization
Manufacturing considerations
Patents
Polimerització
Polímers
Nanocristalls
Cel·lulosa
Materials nanoestructurats
Àrees temàtiques de la UPC::Enginyeria dels materials
Àrees temàtiques de la UPC::Enginyeria química
description Cellulose nanocrystals (CNCs) are an emerging nanomaterial for applications ranging from coatings and construction to adhesives and biomedical devices. Owing to their high aspect ratio, stiffness, and reinforcing potential, CNCs have shown great promise to be used in polymer nanocomposites. However, due to their inherent hydrophilicity and compatibility with polar environments, the use of CNCs in hydrophobic polymer matrices or in organic solvent-based formulations has been limited. To overcome this incompatibility, many reports on grafting polymers onto the surface of CNCs have been published over the past ten years. This review describes the recent advances in CNC surface functionalization through polymer grafting, and comprehensively covers the existing work to date. Methods including polymer “grafting to” and “grafting from” are described in detail, using polymerization techniques such as free radical, ring opening, and controlled radical polymerization. Purification and characterization of polymer-grafted CNCs, the potential for upscaling these functionalization methods, and current perspectives from academic and industrial viewpoints are presented
publishDate 2019
dc.date.none.fl_str_mv 2019
2019-04-01
2021
2021-02-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/336265
https://dx.doi.org/10.1016/j.cossms.2018.11.005
url https://hdl.handle.net/2117/336265
https://dx.doi.org/10.1016/j.cossms.2018.11.005
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivates 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivates 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.301603

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