The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion

[EN] A new route to obtain pillared, disordered or desilicated MWW-type zeolites was developed assisted by quaternary ammonium surfactants with different hydrocarbon tail size acting as swelling agents (C(12)TA(+), C(I6)TA(+), C(18)TA(+)) and TPA(+) both exchanged to their hydroxide forms instead of...

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Detalles Bibliográficos
Autores: Schwanke, Anderson Joel, Pergher, Sibele, Díaz, Urbano|||0000-0003-1472-8724, Corma Canós, Avelino|||0000-0002-2232-3527
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/105502
Acceso en línea:https://riunet.upv.es/handle/10251/105502
Access Level:acceso abierto
Palabra clave:MWW zeolites
Swelling
Pillaring
Hierarchical materials
Fructose dehydration
QUIMICA ORGANICA
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repository_id_str
spelling The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversionSchwanke, Anderson JoelPergher, SibeleDíaz, Urbano|||0000-0003-1472-8724Corma Canós, Avelino|||0000-0002-2232-3527MWW zeolitesSwellingPillaringHierarchical materialsFructose dehydrationQUIMICA ORGANICA[EN] A new route to obtain pillared, disordered or desilicated MWW-type zeolites was developed assisted by quaternary ammonium surfactants with different hydrocarbon tail size acting as swelling agents (C(12)TA(+), C(I6)TA(+), C(18)TA(+)) and TPA(+) both exchanged to their hydroxide forms instead of only one swelling agent (C(n)TA(+) or TPA(+)) in hydroxide form. Effect of surfactant concentration and swelling conditions were determinant to obtain MWW-type zeolites with different lamellar organization and spatial distribution of individual zeolitic layers. Specifically, soft swelling at 25 degrees C with C(12)TA(+) preserved layer structure reaching a final disordered/pillared structure while pillared structures are obtained in the case of materials swollen with C(16)TA(+) and C(18)TA(+). Aggressive swelling processes at 80 degrees C favored desilication, damaging the layers structure in case of C(12)TA(+) while pillared materials are obtained after swollen with C(16)TA(+) and C(18)TA(+) surfactants. It was proved that both swelling agents in hydroxide forms combining with swelling and pillaring procedure influenced on physico-chemical and morphological nature of MWW-type materials due to the particular conditions used. The obtained derivative MWW zeolites with different morphology, order and accessibility levels were firstly evaluated by catalytic dehydration of fructose to 5-hydroxymethylfurfural (5-HMF) showing superior activity compared to beta zeolites reported in literature.Anderson Joel Schwanke is grateful to CAPES Foundation and PDSE program (process number 99999.004779/2014-02) from Ministry of Education of Brazil. U.D and A.C acknowledge to the Spanish Government (Severo Ochoa program SEV-2012-0267 and MAT2014-52085-C2-1-P) and to the Generalitat Valenciana (Prometeo 11/2013-011) by the funding. The European Union is also acknowledged by ERC-AdG-2014-671093 - SynCatMatch.ElsevierInstituto Universitario Mixto de Tecnología QuímicaCoordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, BrasilGeneralitat ValencianaMinistério da Educação, BrazilMinisterio de Economía y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20172017-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/105502reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengEuropean Commission https://doi.org/10.13039/501100000780 H2020 671093 MATching zeolite SYNthesis with CATalytic activityMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2014-52085-C2-1-P NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOSMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 SEV-2012-0267Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2013%2F011 Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas (PROMETEO)Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil https://doi.org/10.13039/501100002322 99999.004779%2F2014-02open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1055022026-06-13T07:49:27Z
dc.title.none.fl_str_mv The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
title The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
spellingShingle The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
Schwanke, Anderson Joel
MWW zeolites
Swelling
Pillaring
Hierarchical materials
Fructose dehydration
QUIMICA ORGANICA
title_short The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
title_full The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
title_fullStr The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
title_full_unstemmed The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
title_sort The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion
dc.creator.none.fl_str_mv Schwanke, Anderson Joel
Pergher, Sibele
Díaz, Urbano|||0000-0003-1472-8724
Corma Canós, Avelino|||0000-0002-2232-3527
author Schwanke, Anderson Joel
author_facet Schwanke, Anderson Joel
Pergher, Sibele
Díaz, Urbano|||0000-0003-1472-8724
Corma Canós, Avelino|||0000-0002-2232-3527
author_role author
author2 Pergher, Sibele
Díaz, Urbano|||0000-0003-1472-8724
Corma Canós, Avelino|||0000-0002-2232-3527
author2_role author
author
author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil
Generalitat Valenciana
Ministério da Educação, Brazil
Ministerio de Economía y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv MWW zeolites
Swelling
Pillaring
Hierarchical materials
Fructose dehydration
QUIMICA ORGANICA
topic MWW zeolites
Swelling
Pillaring
Hierarchical materials
Fructose dehydration
QUIMICA ORGANICA
description [EN] A new route to obtain pillared, disordered or desilicated MWW-type zeolites was developed assisted by quaternary ammonium surfactants with different hydrocarbon tail size acting as swelling agents (C(12)TA(+), C(I6)TA(+), C(18)TA(+)) and TPA(+) both exchanged to their hydroxide forms instead of only one swelling agent (C(n)TA(+) or TPA(+)) in hydroxide form. Effect of surfactant concentration and swelling conditions were determinant to obtain MWW-type zeolites with different lamellar organization and spatial distribution of individual zeolitic layers. Specifically, soft swelling at 25 degrees C with C(12)TA(+) preserved layer structure reaching a final disordered/pillared structure while pillared structures are obtained in the case of materials swollen with C(16)TA(+) and C(18)TA(+). Aggressive swelling processes at 80 degrees C favored desilication, damaging the layers structure in case of C(12)TA(+) while pillared materials are obtained after swollen with C(16)TA(+) and C(18)TA(+) surfactants. It was proved that both swelling agents in hydroxide forms combining with swelling and pillaring procedure influenced on physico-chemical and morphological nature of MWW-type materials due to the particular conditions used. The obtained derivative MWW zeolites with different morphology, order and accessibility levels were firstly evaluated by catalytic dehydration of fructose to 5-hydroxymethylfurfural (5-HMF) showing superior activity compared to beta zeolites reported in literature.
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/105502
url https://riunet.upv.es/handle/10251/105502
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission https://doi.org/10.13039/501100000780 H2020 671093 MATching zeolite SYNthesis with CATalytic activity
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2014-52085-C2-1-P NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 SEV-2012-0267
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2013%2F011 Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas (PROMETEO)
Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil https://doi.org/10.13039/501100002322 99999.004779%2F2014-02
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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