Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives

Producción Científica

Detalles Bibliográficos
Autores: Gutiérrez Loriente, Agustín, Martín Álvarez, José Miguel, Prieto, Elena, Andrés Juan, Celia, Nieto Román, Francisco Javier
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/38103
Acceso en línea:https://doi.org/10.1002/adsc.201801454
http://uvadoc.uva.es/handle/10324/38103
Access Level:acceso abierto
Palabra clave:Síntesis asimétrica
Metátesis
Asymmetric synthesis
Metathesis
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spelling Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine DerivativesGutiérrez Loriente, AgustínMartín Álvarez, José MiguelPrieto, ElenaAndrés Juan, CeliaNieto Román, Francisco JavierSíntesis asimétricaMetátesisAsymmetric synthesisMetathesisProducción CientíficaDiastereoselective ring‐closing metathesis reactions on chiral trienic perhydro‐1,3‐benzoxazines derived from (−)‐8‐aminomenthol featuring two diastereotopic olefin chains is described. The diastereochemical outcome of the cyclization appeared to be dependent on the length and position of the olefin chains in perhydro‐1,3‐benzoxazine, the degree of substitution of the double bonds and the ruthenium catalyst used. After separation of the diastereomers, and removal of the chiral auxiliary, enantiopure oxygen‐ and nitrogen‐containing heterocycles were obtained.Ministerio de Economía, Industria y Competitividad (Project FEDER-CTQ2014-59870-P)Junta de Castilla y León (Ref. Project FEDER-VA115P17)Wiley2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://doi.org/10.1002/adsc.201801454http://uvadoc.uva.es/handle/10324/38103reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://onlinelibrary.wiley.com/doi/10.1002/adsc.201801454info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/oai:uvadoc.uva.es:10324/381032026-06-13T12:44:47Z
dc.title.none.fl_str_mv Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
title Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
spellingShingle Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
Gutiérrez Loriente, Agustín
Síntesis asimétrica
Metátesis
Asymmetric synthesis
Metathesis
title_short Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
title_full Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
title_fullStr Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
title_full_unstemmed Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
title_sort Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
dc.creator.none.fl_str_mv Gutiérrez Loriente, Agustín
Martín Álvarez, José Miguel
Prieto, Elena
Andrés Juan, Celia
Nieto Román, Francisco Javier
author Gutiérrez Loriente, Agustín
author_facet Gutiérrez Loriente, Agustín
Martín Álvarez, José Miguel
Prieto, Elena
Andrés Juan, Celia
Nieto Román, Francisco Javier
author_role author
author2 Martín Álvarez, José Miguel
Prieto, Elena
Andrés Juan, Celia
Nieto Román, Francisco Javier
author2_role author
author
author
author
dc.subject.none.fl_str_mv Síntesis asimétrica
Metátesis
Asymmetric synthesis
Metathesis
topic Síntesis asimétrica
Metátesis
Asymmetric synthesis
Metathesis
description Producción Científica
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1002/adsc.201801454
http://uvadoc.uva.es/handle/10324/38103
url https://doi.org/10.1002/adsc.201801454
http://uvadoc.uva.es/handle/10324/38103
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://onlinelibrary.wiley.com/doi/10.1002/adsc.201801454
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.301603

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