Efficient functionalization of quinolizinium cations with organotrifluoroborates in water
An efficient functionalization of the quinolizinium system is reported. The reaction of the four isomeric bromoquinolizinium salts with different organotrifluoroborates afforded alkyl-, vinyl-, aryl-, and heteroaryl quinolizinium derivatives in moderate or good yields. Reactions are carried out in w...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2009 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/2678 |
| Acceso en línea: | http://hdl.handle.net/10017/2678 https://dx.doi.org/10.1016/j.tetlet.2009.01.040 |
| Access Level: | acceso abierto |
| Palabra clave: | Quinolizinium Efficient functionalization Organotrifluoroborates Water Bioquímica Ciencia Biochemistry Science |
| Sumario: | An efficient functionalization of the quinolizinium system is reported. The reaction of the four isomeric bromoquinolizinium salts with different organotrifluoroborates afforded alkyl-, vinyl-, aryl-, and heteroaryl quinolizinium derivatives in moderate or good yields. Reactions are carried out in water using a counterion exchange for the isolation of the cationic-coupled compounds. |
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