The Enskog Equation for Confined Elastic Hard Spheres

A kinetic equation for a system of elastic hard spheres or disks confined by a hard wall of arbitrary shape is derived. It is a generalization of the modified Enskog equation in which the effects of the confinement are taken into account and it is supposed to be valid up to moderate densities. From...

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Detalles Bibliográficos
Autores: Maynar Blanco, Pablo, García de Soria Lucena, María Isabel, Brey Abalo, José Javier
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/104304
Acceso en línea:https://hdl.handle.net/11441/104304
https://doi.org/10.1007/s10955-018-1971-7
Access Level:acceso abierto
Palabra clave:Enskog equation
H-theorem
Hard-sphere fluid
Kinetic theory
Descripción
Sumario:A kinetic equation for a system of elastic hard spheres or disks confined by a hard wall of arbitrary shape is derived. It is a generalization of the modified Enskog equation in which the effects of the confinement are taken into account and it is supposed to be valid up to moderate densities. From the equation, balance equations for the hydrodynamic fields are derived, identifying the collisional transfer contributions to the pressure tensor and heat flux. A Lyapunov functional, H[ f] , is identified. For any solution of the kinetic equation, H decays monotonically in time until the system reaches the inhomogeneous equilibrium distribution, that is a Maxwellian distribution with a density field consistent with equilibrium statistical mechanics.