Tailor-Made Synthesis of Hydrosilanols, Hydrosiloxanes, and Silanediols Catalyzed by di-Silyl Rhodium(III) and Iridium(III) Complexes
Siloxanes and silanols containing Si–H units are important building blocks for the synthesis of functionalized siloxane materials, and their synthesis is a current challenge. Herein, we report the selective synthesis of hydrosilanols, hydrosiloxanes, and silanodiols depending on the nature of the ca...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Universidad del País Vasco |
| Repositorio: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/65188 |
| Acceso en línea: | http://hdl.handle.net/10810/65188 |
| Access Level: | acceso abierto |
| Palabra clave: | catalysts chemical reactions condensation group 14 compounds hydrolysis |
| Sumario: | Siloxanes and silanols containing Si–H units are important building blocks for the synthesis of functionalized siloxane materials, and their synthesis is a current challenge. Herein, we report the selective synthesis of hydrosilanols, hydrosiloxanes, and silanodiols depending on the nature of the catalysts and the silane used. Two neutral ({MCl[SiMe2(o-C6H4PPh2)]2}; M = Rh, Ir) and two cationic ({M[SiMe2(o-C6H4PPh2)]2(NCMe)}[BArF4]; M = Rh, Ir) have been synthesized and their catalytic behavior toward hydrolysis of secondary silanes has been described. Using the iridium complexes as precatalysts and diphenylsilane as a substrate, the product obtained is diphenylsilanediol. When rhodium complexes are used as precatalysts, it is possible to selectively obtain silanediol, hydrosilanol, and hydrosiloxane depending on the catalysts (neutral or cationic) and the silane substituents |
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