Revisiting N2-N2 collisional linewidth models for S-branch rotational Raman scattering

This paper presents an evaluation of two commonly accepted Raman linewidth models typically used to fit CARS model parameters to data; the Modified Exponential Gap (MEG) and the Energy Corrected Sudden (ECS) models. The adjustable parameters in each model have been fit to published experimental line...

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Detalles Bibliográficos
Autores: Linne, Mark, Mecker, Nils Torge, Kliewer, Christopher, Escofet Martín, David|||0000-0001-8943-6123, Peterson, Brian
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/407321
Acceso en línea:https://hdl.handle.net/2117/407321
https://dx.doi.org/10.1016/j.combustflame.2021.111928
Access Level:acceso abierto
Palabra clave:Raman spectroscopy
Temperature measurements
Espectroscòpia Raman
Termometria
Àrees temàtiques de la UPC::Física::Termodinàmica
Descripción
Sumario:This paper presents an evaluation of two commonly accepted Raman linewidth models typically used to fit CARS model parameters to data; the Modified Exponential Gap (MEG) and the Energy Corrected Sudden (ECS) models. The adjustable parameters in each model have been fit to published experimental linewidths, and comparisons are made to the various publications that have already provided similar adjustable constants. The approaches presented in the literature are discussed as are differences with the findings presented here.