Photoinduced electron transfer in Nano-Saturn complexes of fullerene
The photoinduced electron transfer is studied computationally in several Saturn-shaped inclusion complexes of carbo-aromatic rings and C60 fullerene - C72⊃C60, C96⊃C60, C120⊃C60, and C168⊃C60. Analysis of their structural and electronic properties shows that the charge separation process is efficien...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2021 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:10256/19069 |
| Acceso en línea: | http://hdl.handle.net/10256/19069 |
| Access Level: | acceso abierto |
| Palabra clave: | Transferència de càrrega Ful·lerens Electrons Charge transfer Fullerenes Electrones |
| Sumario: | The photoinduced electron transfer is studied computationally in several Saturn-shaped inclusion complexes of carbo-aromatic rings and C60 fullerene - C72⊃C60, C96⊃C60, C120⊃C60, and C168⊃C60. Analysis of their structural and electronic properties shows that the charge separation process is efficient in C120⊃C60 and C168⊃C60 where the host molecule resembles the conjugated [24]circulene unit. In contrast, the electron transfer is not feasible in the oligophenylene-based rings C72⊃C60 and C96⊃C60 complexes |
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