Fibrous clays based bionanocomposites

Sepiolite and palygorskite are natural microfibrous clay minerals whose particular structural, morphological and textural features are useful for the preparation of a wide variety of advanced nanostructured materials, essentially regarding their ability to render nanocomposite materials. The silanol...

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Autores: Ruiz-Hitzky, Eduardo, Darder, Margarita, Fernandes, Francisco M., Wicklein, Bernd, Alcântara, Ana C. S., Aranda, Pilar
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2013
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/94272
Acceso en línea:http://hdl.handle.net/10261/94272
Access Level:acceso abierto
Palabra clave:Palygorskite
Sepiolite
Biopolymers
Fibrous clays
Bionanocomposites
Biohybrids
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spelling Fibrous clays based bionanocompositesRuiz-Hitzky, EduardoDarder, MargaritaFernandes, Francisco M.Wicklein, BerndAlcântara, Ana C. S.Aranda, PilarPalygorskiteSepioliteBiopolymersFibrous claysBionanocompositesBiohybridsSepiolite and palygorskite are natural microfibrous clay minerals whose particular structural, morphological and textural features are useful for the preparation of a wide variety of advanced nanostructured materials, essentially regarding their ability to render nanocomposite materials. The silanol groups located on the external surface of these silicates and their surface electrical charge are the centers for interactions with biopolymers, such as polysaccharides, proteins, lipids and nucleic acids. In the present review we introduce recent results from sepiolite- and palygorskite-based bionanocomposites showing the interest of these silicates compared to lamellar clays for diverse applications such as bioplastics and membranes, uses in biomedicine as drug delivery systems and adjuvants of vaccines as well as in tissue engineering. Other applications here discussed focus on environmental purposes, the use of bionanocomposites as components of sensor devices and bioreactors and as source of supported graphene. © 2013 Elsevier Ltd.The authors are indebted to the CICYT (Spain, projects MAT2009-09960, and MAT2012-31759) and the CSIC (projects PIF08-018 and 2010MA0003 CSIC-Academie Hassan II). ACSA acknowledges the CSIC (Spain) for her JAE-Predoc fellowship.Peer reviewedPeer ReviewedElsevierComisión Interministerial de Ciencia y Tecnología, CICYT (España)Consejo Superior de Investigaciones Científicas (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2014201420132014info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/94272reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésInglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MICINN//MAT2009-09960info:eu-repo/grantAgreement//MAT2012-31759/https://doi.org/10.1016/j.progpolymsci.2013.05.004Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/942722026-05-22T06:33:51Z
dc.title.none.fl_str_mv Fibrous clays based bionanocomposites
title Fibrous clays based bionanocomposites
spellingShingle Fibrous clays based bionanocomposites
Ruiz-Hitzky, Eduardo
Palygorskite
Sepiolite
Biopolymers
Fibrous clays
Bionanocomposites
Biohybrids
title_short Fibrous clays based bionanocomposites
title_full Fibrous clays based bionanocomposites
title_fullStr Fibrous clays based bionanocomposites
title_full_unstemmed Fibrous clays based bionanocomposites
title_sort Fibrous clays based bionanocomposites
dc.creator.none.fl_str_mv Ruiz-Hitzky, Eduardo
Darder, Margarita
Fernandes, Francisco M.
Wicklein, Bernd
Alcântara, Ana C. S.
Aranda, Pilar
author Ruiz-Hitzky, Eduardo
author_facet Ruiz-Hitzky, Eduardo
Darder, Margarita
Fernandes, Francisco M.
Wicklein, Bernd
Alcântara, Ana C. S.
Aranda, Pilar
author_role author
author2 Darder, Margarita
Fernandes, Francisco M.
Wicklein, Bernd
Alcântara, Ana C. S.
Aranda, Pilar
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Comisión Interministerial de Ciencia y Tecnología, CICYT (España)
Consejo Superior de Investigaciones Científicas (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Palygorskite
Sepiolite
Biopolymers
Fibrous clays
Bionanocomposites
Biohybrids
topic Palygorskite
Sepiolite
Biopolymers
Fibrous clays
Bionanocomposites
Biohybrids
description Sepiolite and palygorskite are natural microfibrous clay minerals whose particular structural, morphological and textural features are useful for the preparation of a wide variety of advanced nanostructured materials, essentially regarding their ability to render nanocomposite materials. The silanol groups located on the external surface of these silicates and their surface electrical charge are the centers for interactions with biopolymers, such as polysaccharides, proteins, lipids and nucleic acids. In the present review we introduce recent results from sepiolite- and palygorskite-based bionanocomposites showing the interest of these silicates compared to lamellar clays for diverse applications such as bioplastics and membranes, uses in biomedicine as drug delivery systems and adjuvants of vaccines as well as in tissue engineering. Other applications here discussed focus on environmental purposes, the use of bionanocomposites as components of sensor devices and bioreactors and as source of supported graphene. © 2013 Elsevier Ltd.
publishDate 2013
dc.date.none.fl_str_mv 2013
2014
2014
2014
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/94272
url http://hdl.handle.net/10261/94272
dc.language.none.fl_str_mv Inglés
Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MICINN//MAT2009-09960
info:eu-repo/grantAgreement//MAT2012-31759/
https://doi.org/10.1016/j.progpolymsci.2013.05.004
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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