Bioavailability, Bioaccesibility of Heavy Metal Elements and Speciation of as in Contaminated Areas of Chile

Studies on the bioavailability of As, Cr, Cu, Pb, Mn and Cd of impacted soils; the As bioaccesibility in the edible parts of carrots, beets and quinoa growing in these polluted soils thought “in vitro” gastrointestinal process; the As speciation both in the edible parts of vegetables and in their ga...

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Detalles Bibliográficos
Autores: Pizarro, Isabel, Gómez Gómez, María Milagros, Román, Domingo, Palacios Corvillo, M.Antonia
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/23404
Acceso en línea:https://hdl.handle.net/20.500.14352/23404
Access Level:acceso abierto
Palabra clave:543
Arsenic
Heavy metals
Bioaccesibility
Bioavailability
Soils
Carrots (Daucus carota)
Beets (Beta vulgaris)
Quinoa (Chenopodium)
In vitro gastrointestinal digestion
As speciation
ICPMS
Química analítica (Química)
2301 Química Analítica
Descripción
Sumario:Studies on the bioavailability of As, Cr, Cu, Pb, Mn and Cd of impacted soils; the As bioaccesibility in the edible parts of carrots, beets and quinoa growing in these polluted soils thought “in vitro” gastrointestinal process; the As speciation both in the edible parts of vegetables and in their gastrointestinal extracts have been performed. Elemental analysis and As speciation have been performed by ICP-MS and LC-ICP-MS, respectively. The high As contents in the interchangeable and oxidized fractions of soil may be responsible for the high As species content in these high vegetables consumption. The Arsenic recovery after the in vitro gastrointestinal digestion was from 98, 90 and 40% for carrots, beets and quinoa, respectively; with no significant transformation of original As species. These studies provide a clearer understanding of the impact that As and other contaminant elements may present in the population of this high polluted Chilean region.