Development of crayfish protein-PCL biocomposite material processed by injection moulding

A combination of crayfish flour (CF, with 60% protein) and Polycaprolactone (PCL) was successfully used to prepare biocomposites by a process that consists of two stages: mixing with glycerol (GL) as plasticizer and injection moulding of CF/GL/PCL blends. Mixing rheometry and Differential Scanning C...

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Detalhes bibliográficos
Autores: Félix Ángel, Manuel, Romero García, Alberto, Martín Alfonso, José Enrique, Guerrero Conejo, Antonio Francisco
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2015
País:España
Recursos:Universidad de Sevilla (US)
Repositório:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/172702
Acesso em linha:https://hdl.handle.net/11441/172702
https://doi.org/10.1016/j.compositesb.2015.03.057
Access Level:Acceso aberto
Palavra-chave:A. Polymer-matrix composites (PMCs)
B. Rheological properties
B. Thermomechanical
E. Injection moulding
Descrição
Resumo:A combination of crayfish flour (CF, with 60% protein) and Polycaprolactone (PCL) was successfully used to prepare biocomposites by a process that consists of two stages: mixing with glycerol (GL) as plasticizer and injection moulding of CF/GL/PCL blends. Mixing rheometry and Differential Scanning Calorimetry (DSC) measurements were found to be useful to select suitable injection moulding conditions. A remarkable enhancement in mechanical properties was found for PCL containing systems, even when crystalline structure remains unaltered. PCL yields a dominant contribution to the elastic response and confer a higher ability to absorb energy before rupture, but also the protein/plasticiser ratio must be considered.