Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach

17 pages, 11 figures, 10 tables

Detalhes bibliográficos
Autores: Maestro-Guijarro, Laura, Pinilla, Alejandro, Carmona-Quiroga, Paula, Agua Martínez, Fernando, Castillejo, Marta, García Heras, Manuel, Oujja, Mohamed, Villegas Broncano, María Ángeles
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/380008
Acesso em linha:http://hdl.handle.net/10261/380008
https://api.elsevier.com/content/abstract/scopus_id/85213829113
Access Level:acceso abierto
Palavra-chave:Authentication
Chromophores
Contemporary commercial beads
Historical glass beads
Multi-analytical approach
Opacifiers
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network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
title Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
spellingShingle Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
Maestro-Guijarro, Laura
Authentication
Chromophores
Contemporary commercial beads
Historical glass beads
Multi-analytical approach
Opacifiers
title_short Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
title_full Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
title_fullStr Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
title_full_unstemmed Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
title_sort Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approach
dc.creator.none.fl_str_mv Maestro-Guijarro, Laura
Pinilla, Alejandro
Carmona-Quiroga, Paula
Agua Martínez, Fernando
Castillejo, Marta
García Heras, Manuel
Oujja, Mohamed
Villegas Broncano, María Ángeles
author Maestro-Guijarro, Laura
author_facet Maestro-Guijarro, Laura
Pinilla, Alejandro
Carmona-Quiroga, Paula
Agua Martínez, Fernando
Castillejo, Marta
García Heras, Manuel
Oujja, Mohamed
Villegas Broncano, María Ángeles
author_role author
author2 Pinilla, Alejandro
Carmona-Quiroga, Paula
Agua Martínez, Fernando
Castillejo, Marta
García Heras, Manuel
Oujja, Mohamed
Villegas Broncano, María Ángeles
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
Comunidad de Madrid
Consejo Superior de Investigaciones Científicas (España)
CSIC - Unidad de Recursos de Información Científica para la Investigación (URICI)
Maestro-Guijarro, Laura `[0000-0002-0530-3815]
#NODATA#
Carmona-Quiroga, Paula [0000-0002-9583-7131]
#NODATA#
Castillejo, Marta [0000-0002-5870-4380]
García-Heras, M. [0000-0002-4468-2694]
Oujja, Mohamed [0000-0003-3757-4043]
Villegas Broncano, María Ángeles [0000-0002-9727-5478]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Authentication
Chromophores
Contemporary commercial beads
Historical glass beads
Multi-analytical approach
Opacifiers
topic Authentication
Chromophores
Contemporary commercial beads
Historical glass beads
Multi-analytical approach
Opacifiers
description 17 pages, 11 figures, 10 tables
publishDate 2025
dc.date.none.fl_str_mv 2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/380008
https://api.elsevier.com/content/abstract/scopus_id/85213829113
url http://hdl.handle.net/10261/380008
https://api.elsevier.com/content/abstract/scopus_id/85213829113
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-137017OB-I00
TEC-2024/TEC-39/Heritage-CM
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123721OB-I00
Talanta
Maestro-Guijarro, Laura, Pinilla Gisbert, Alejandro, Carmona-Quiroga, Paula, Agua Martínez, Fernando, Castillejo, Marta, García Heras, Manuel, Oujja, Mohamed, Villegas Broncano, María Ángeles; 2025;"Analysis of glass beads from Cultural Heritage for authentication purposes [Dataset]"; DIGITAL.CSIC; 10.20350/digitalCSIC/17537
https://doi.org/10.1016/j.talanta.2024.127510
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
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spelling Authentication of glass beads from Cultural Heritage: An interdisciplinary and multi-analytical approachMaestro-Guijarro, LauraPinilla, AlejandroCarmona-Quiroga, PaulaAgua Martínez, FernandoCastillejo, MartaGarcía Heras, ManuelOujja, MohamedVillegas Broncano, María ÁngelesAuthenticationChromophoresContemporary commercial beadsHistorical glass beadsMulti-analytical approachOpacifiers17 pages, 11 figures, 10 tablesAnalysis of glass-based artworks is important for authentication purposes. In recent years, there have been rapid advancements and improvements in the characterization of glass objects using different analytical approaches. The present study presents an interdisciplinary and multi-analytical authentication approach that provides useful tools and markers to unmask possible imitations, counterfeiting, and forgeries in Cultural Heritage glass beads by comparing the composition of historical and modern glass beads. The approach includes the use of binocular magnifying glass, X-ray Fluorescence (XRF), Field Emission Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy (FESEM-EDS), UV-Vis spectrophotometry, X-ray diffraction (XRD) and Laser Induced Breakdown Spectroscopy (LIBS) techniques. Resulting data indicate that antimony, when detected, is only present in historical beads, while boron, zinc, and/or molybdenum are only detected as possible components in modern beads. As marker chromophores for historical beads, lead antimoniate or iron are responsible for yellow, copper for red, and iron and/or copper for green colors. Modern beads coloration was attributed to the presence of cadmium sulfoselenide microparticles for yellow to red colors and chromium for green colors. Opacity in historical beads was generated by dispersed tin oxide or calcium antimoniate microcrystals, while in modern beads the opacity is related to ZrO2 microcrystals and/or fluorine ions. In this study, LIBS has been validated and proven feasible for in situ exploring analytical parameters that can be useful for authentication purposes of historical glass objects, regardless of their size, provenance, and chronology.This research has been funded by MCIN/AEI/10.13039/ 501100011033/FEDER, UE through the project PID2022-137017OB- I00 and by the Regional Government of Madrid through the project TEC Heritage-CM (TEC-2024/TEC-39), and supported by the CSIC Interdisciplinary Platform “Open Heritage: Research and Society” (PTI- PAIS). The authors acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI). A. Pinilla Gisbert acknowledges a PhD contract from the Regional Government of Madrid (PIPF- 2023/PH-HUM-29465). Glass beads from the oppidum of Ulaca (´ Avila, Spain) were unearthed through systematic archaeological excavations undertaken by Drs. J.R. ´ Alvarez-Sanchís and J. Rodríguez-Hernandez within the framework of the project URBADEN (PID2021-123721OB- I00) funded by MCIN/AEI/10.13039/501100011033/FEDER, UE. The glass bead of Cubillejo de la Sierra (Guadalajara, Spain) comes from systematic excavations lead by Dr. M. Cerdeno and funded by the Guadalajara Provincial Council. Glass beads from the Ibo Island (Mozambique) have been possible within the framework of a research program developed by a Spanish archaeological team led by Dr. M. Ruiz- G´ alvez in cooperation with the Eduardo Mondlane University, which undertook systematic archaeological excavations from 2015 to 2017 funded by the Spanish Ministry of Economy, Industry and Competitiveness through the National Program for Fostering Excellence in Scientific and Technical Research (HAR2013-48495-C2-2-P), the International Archaeological Excavations scheme from the Spanish Cultural Heritage Institute (IPCE), and the Palarq Foundation. Mozambican Heritage authorities are gratefully acknowledged for giving permission to export the glass beads to Spain. The authors especially thank Drs. M. Ruiz-G´ alvez, J.R. ´ Alvarez-Sanchís and M. Cerdeno for providing them with the historical glass bead samples.Peer reviewedElsevierMinisterio de Ciencia e Innovación (España)Comunidad de MadridConsejo Superior de Investigaciones Científicas (España)CSIC - Unidad de Recursos de Información Científica para la Investigación (URICI)Maestro-Guijarro, Laura `[0000-0002-0530-3815]#NODATA#Carmona-Quiroga, Paula [0000-0002-9583-7131]#NODATA#Castillejo, Marta [0000-0002-5870-4380]García-Heras, M. [0000-0002-4468-2694]Oujja, Mohamed [0000-0003-3757-4043]Villegas Broncano, María Ángeles [0000-0002-9727-5478]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252025info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/380008https://api.elsevier.com/content/abstract/scopus_id/85213829113reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-137017OB-I00TEC-2024/TEC-39/Heritage-CMinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123721OB-I00TalantaMaestro-Guijarro, Laura, Pinilla Gisbert, Alejandro, Carmona-Quiroga, Paula, Agua Martínez, Fernando, Castillejo, Marta, García Heras, Manuel, Oujja, Mohamed, Villegas Broncano, María Ángeles; 2025;"Analysis of glass beads from Cultural Heritage for authentication purposes [Dataset]"; DIGITAL.CSIC; 10.20350/digitalCSIC/17537https://doi.org/10.1016/j.talanta.2024.127510Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3800082026-05-22T06:33:51Z
score 15,811543

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