Stereospecific carbene polymerisation with oxygenated Rh(diene) species

Breath-taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2-rhodaoxetane intermediates. This discovery gives...

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Autores: Walters, Annemarie J. C., Troeppner, Oliver, Ivanović-Burmazović, Ivana, Tejel, Cristina, Río, M. Pilar del, Reek, Joost N. H., Bruin, Bas de
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2012
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/108700
Acceso en línea:http://hdl.handle.net/10261/108700
Access Level:acceso abierto
Palabra clave:Diazo compounds
Oxidation
Polymerization
Rhodium
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spelling Stereospecific carbene polymerisation with oxygenated Rh(diene) speciesWalters, Annemarie J. C.Troeppner, OliverIvanović-Burmazović, IvanaTejel, CristinaRío, M. Pilar delReek, Joost N. H.Bruin, Bas deDiazo compoundsOxidationPolymerizationRhodiumBreath-taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2-rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism.Financial support from the European Research Council (ERC, grant agreement 202886-CatCIR), the Netherlands Organization for Scientific Research (NWO-CW), the Dutch Polymer Institute (DPI projects no. 646/647), the University of Amsterdam, the DFG (SFB-583 and Major Research Instrumentation Program) and MICINN/FEDER (Projects CTQ2008-03860 and CTQ2011-22516) is gratefully acknowledged.Peer ReviewedWiley-VCHEuropean CommissionNetherlands Organization for Scientific ResearchDutch Polymer InstituteUniversity of AmsterdamMinisterio de Ciencia e Innovación (España)2014201420122014info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/108700reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/202886http://dx.doi.org/10.1002/anie.201200069info:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1087002026-05-22T06:33:51Z
dc.title.none.fl_str_mv Stereospecific carbene polymerisation with oxygenated Rh(diene) species
title Stereospecific carbene polymerisation with oxygenated Rh(diene) species
spellingShingle Stereospecific carbene polymerisation with oxygenated Rh(diene) species
Walters, Annemarie J. C.
Diazo compounds
Oxidation
Polymerization
Rhodium
title_short Stereospecific carbene polymerisation with oxygenated Rh(diene) species
title_full Stereospecific carbene polymerisation with oxygenated Rh(diene) species
title_fullStr Stereospecific carbene polymerisation with oxygenated Rh(diene) species
title_full_unstemmed Stereospecific carbene polymerisation with oxygenated Rh(diene) species
title_sort Stereospecific carbene polymerisation with oxygenated Rh(diene) species
dc.creator.none.fl_str_mv Walters, Annemarie J. C.
Troeppner, Oliver
Ivanović-Burmazović, Ivana
Tejel, Cristina
Río, M. Pilar del
Reek, Joost N. H.
Bruin, Bas de
author Walters, Annemarie J. C.
author_facet Walters, Annemarie J. C.
Troeppner, Oliver
Ivanović-Burmazović, Ivana
Tejel, Cristina
Río, M. Pilar del
Reek, Joost N. H.
Bruin, Bas de
author_role author
author2 Troeppner, Oliver
Ivanović-Burmazović, Ivana
Tejel, Cristina
Río, M. Pilar del
Reek, Joost N. H.
Bruin, Bas de
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Netherlands Organization for Scientific Research
Dutch Polymer Institute
University of Amsterdam
Ministerio de Ciencia e Innovación (España)
dc.subject.none.fl_str_mv Diazo compounds
Oxidation
Polymerization
Rhodium
topic Diazo compounds
Oxidation
Polymerization
Rhodium
description Breath-taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2-rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism.
publishDate 2012
dc.date.none.fl_str_mv 2012
2014
2014
2014
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/108700
url http://hdl.handle.net/10261/108700
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/FP7/202886
http://dx.doi.org/10.1002/anie.201200069
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155

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