Influence of La and Ce additions on the magnetocaloric effect of Fe–B–Cr-based amorphous alloys

The magnetic entropy change (ΔSM), temperature of peak ΔSM (Tpk) and refrigerant capacity (RC) in Fe(RE)80B12Cr8 (RE = La, Ce, or Gd) alloys were studied. Increasing La, Ce, and Gd content led to relatively constant, decrease, and increase in Tpk, respectively. Both the phenomenologically constructe...

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Detalles Bibliográficos
Autores: Law, Jia Yan, Franco García, Victorino, Ramanujan, Raju Vijayaraghavan
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2011
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/66867
Acceso en línea:http://hdl.handle.net/11441/66867
https://doi.org/10.1063/1.3589353
Access Level:acceso abierto
Palabra clave:Amorphous state
Boron alloys
Cerium alloys
Chromium alloys
Cirie temperature
Gadolinium alloys
Iron alloys
Lanthanum alloys
Magnetic cooling
Magnetocalorics effects
Descripción
Sumario:The magnetic entropy change (ΔSM), temperature of peak ΔSM (Tpk) and refrigerant capacity (RC) in Fe(RE)80B12Cr8 (RE = La, Ce, or Gd) alloys were studied. Increasing La, Ce, and Gd content led to relatively constant, decrease, and increase in Tpk, respectively. Both the phenomenologically constructed universal curve for ΔSM and field dependence power laws demonstrated that these alloys exhibited similar critical exponents at Curie temperature. With 5% Ce added to Fe80B12Cr8, Tpk could be tuned near room temperature with relatively constant peak ΔSM. Fe79B12Cr8La1 exhibited enhanced RC compared to Gd5Si2Ge1.9Fe0.1. The tunable Tpk and enhanced RC are needed in active magnetic regenerators.