Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments

Additive manufacturing could be an excellent way of shaping magnetocaloric heat exchangers in magnetic refrigerators. However, the metal additive manufacturing techniques present the serious limitation that the melting of a magnetocaloric material can cause its transformation and the loss of functio...

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Detalhes bibliográficos
Autores: Díaz García, Álvaro, Revuelta Losada, Jorge, Moreno Ramírez, Luis Miguel, Law, Jia Yan, Mayer, C., Franco García, Victorino
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2022
País:España
Recursos:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/156472
Acesso em linha:https://hdl.handle.net/11441/156472
https://doi.org/10.1016/j.coco.2022.101352
Access Level:acceso abierto
Palavra-chave:Additive manufacturing
Fused deposition modeling
Magnetocaloric composite
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spelling Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filamentsDíaz García, ÁlvaroRevuelta Losada, JorgeMoreno Ramírez, Luis MiguelLaw, Jia YanMayer, C.Franco García, VictorinoAdditive manufacturingFused deposition modelingMagnetocaloric compositeAdditive manufacturing could be an excellent way of shaping magnetocaloric heat exchangers in magnetic refrigerators. However, the metal additive manufacturing techniques present the serious limitation that the melting of a magnetocaloric material can cause its transformation and the loss of functionality. Fused deposition modeling using polymer-based composite filaments is presented as a promising alternative as temperatures are low enough to preserve the magnetocaloric material. To prove this claim, a polymer-based composite filament containing 55 wt% of (La,Ce)(Fe,Mn,Si)13–H magnetocaloric fillers has been manufactured using custom-made polymer capsules as the feedstock for the extrusion. Both adiabatic temperature change and isothermal entropy change have been characterized for the fillers, as-prepared filaments and as-printed parts, indicating that the magnetocaloric material functionality is not altered along the whole process. Printing resolution is comparable to the raw PLA filament.MCIN/ AEI/10.13039/501100011033 PID2019-105720RB-I00Consejería de Economía, Conocimiento, Empresas y Universidad de la Junta de Andalucía P18-RT-746Air Force Office of Scientific Research (FA8655-21-1-7044)Premio Anual Publicación Científica Destacada de la US. Facultad de FísicaElsevierFísica de la Materia CondensadaMinisterio de Ciencia e Innovación (MICIN). EspañaAgencia Estatal de Investigación. EspañaJunta de AndalucíaAir Force Office of Scientific Research2022info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/156472https://doi.org/10.1016/j.coco.2022.101352reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésComposites Communications, 35, 101352.PID2019-105720RB-I00P18-RT-746FA8655-21-1-7044https://dx.doi.org/10.1016/j.coco.2022.101352info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1564722026-06-17T12:51:07Z
dc.title.none.fl_str_mv Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
title Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
spellingShingle Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
Díaz García, Álvaro
Additive manufacturing
Fused deposition modeling
Magnetocaloric composite
title_short Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
title_full Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
title_fullStr Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
title_full_unstemmed Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
title_sort Additive manufacturing of magnetocaloric (La,Ce)(Fe,Mn,Si)13–H particles via polymer-based composite filaments
dc.creator.none.fl_str_mv Díaz García, Álvaro
Revuelta Losada, Jorge
Moreno Ramírez, Luis Miguel
Law, Jia Yan
Mayer, C.
Franco García, Victorino
author Díaz García, Álvaro
author_facet Díaz García, Álvaro
Revuelta Losada, Jorge
Moreno Ramírez, Luis Miguel
Law, Jia Yan
Mayer, C.
Franco García, Victorino
author_role author
author2 Revuelta Losada, Jorge
Moreno Ramírez, Luis Miguel
Law, Jia Yan
Mayer, C.
Franco García, Victorino
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Física de la Materia Condensada
Ministerio de Ciencia e Innovación (MICIN). España
Agencia Estatal de Investigación. España
Junta de Andalucía
Air Force Office of Scientific Research
dc.subject.none.fl_str_mv Additive manufacturing
Fused deposition modeling
Magnetocaloric composite
topic Additive manufacturing
Fused deposition modeling
Magnetocaloric composite
description Additive manufacturing could be an excellent way of shaping magnetocaloric heat exchangers in magnetic refrigerators. However, the metal additive manufacturing techniques present the serious limitation that the melting of a magnetocaloric material can cause its transformation and the loss of functionality. Fused deposition modeling using polymer-based composite filaments is presented as a promising alternative as temperatures are low enough to preserve the magnetocaloric material. To prove this claim, a polymer-based composite filament containing 55 wt% of (La,Ce)(Fe,Mn,Si)13–H magnetocaloric fillers has been manufactured using custom-made polymer capsules as the feedstock for the extrusion. Both adiabatic temperature change and isothermal entropy change have been characterized for the fillers, as-prepared filaments and as-printed parts, indicating that the magnetocaloric material functionality is not altered along the whole process. Printing resolution is comparable to the raw PLA filament.
publishDate 2022
dc.date.none.fl_str_mv 2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/156472
https://doi.org/10.1016/j.coco.2022.101352
url https://hdl.handle.net/11441/156472
https://doi.org/10.1016/j.coco.2022.101352
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Composites Communications, 35, 101352.
PID2019-105720RB-I00
P18-RT-746
FA8655-21-1-7044
https://dx.doi.org/10.1016/j.coco.2022.101352
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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