Reorientation of single-wall carbon nanotubes in negative anisotropy liquid crystals by an electric field

Single-wall carbon nanotubes (SWCNT) are anisotropic nanoparticles that can cause modifications in the electrical and electro-optical properties of liquid crystals. The control of the SWCNT concentration, distribution and reorientation in such self-organized fluids allows for the possibility of tuni...

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Detalles Bibliográficos
Autores: García García, Amanda, Vergaz Benito, Ricardo, Algorri Genaro, José Francisco|||0000-0002-2654-583X, Zito, Gianluigi, Cacace, Teresa, Marino, Antigone, Otón Sánchez, José Manuel, Geday, Morten Andreas
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad de Cantabria (UC)
Repositorio:UCrea Repositorio Abierto de la Universidad de Cantabria
Idioma:inglés
OAI Identifier:oai:repositorio.unican.es:10902/28997
Acceso en línea:https://hdl.handle.net/10902/28997
Access Level:acceso abierto
Palabra clave:Carbon nanotubes
Impedance
Liquid crystal
Negative anisotropy
Raman spectroscopy
Reorientation
Single-wall CNTs
Descripción
Sumario:Single-wall carbon nanotubes (SWCNT) are anisotropic nanoparticles that can cause modifications in the electrical and electro-optical properties of liquid crystals. The control of the SWCNT concentration, distribution and reorientation in such self-organized fluids allows for the possibility of tuning the liquid crystal properties. The alignment and reorientation of CNTs are studied in a system where the liquid crystal orientation effect has been isolated. Complementary studies including Raman spectroscopy, microscopic inspection and impedance studies were carried out. The results reveal an ordered reorientation of the CNTs induced by an electric field, which does not alter the orientation of the liquid crystal molecules. Moreover, impedance spectroscopy suggests a nonnegligible anchoring force between the CNTs and the liquid crystal molecules.