Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films

Producción Científica

Detalles Bibliográficos
Autores: Domínguez, Cristina, Baena Alonso, María Jesús, Coco Cea, Silverio, Espinet Rubio, Pablo
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/33434
Acceso en línea:https://doi.org/10.1016/j.dyepig.2017.01.057
http://uvadoc.uva.es/handle/10324/33434
Access Level:acceso abierto
Palabra clave:Tinte organometálico
Organometallic dye
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spelling Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir FilmsDomínguez, CristinaBaena Alonso, María JesúsCoco Cea, SilverioEspinet Rubio, PabloTinte organometálicoOrganometallic dyeProducción CientíficaA new perylenediimide-isocyanide N,N’-bis(1-ethylpropyl)-1-isocyanide-perylene-3,4:9,10-bis(dicarboximide) (CN-PDI), as well as the isocyanide [AuY(CN-PDI)] and carbene [Au-Y-{C(NH-PDI) (NMe2)}] (Y = Cl, C6F5, 4-C6F4OC6H13, 1/2-μ-C6F4C6F4) gold complexes therefrom, have been synthesized and characterized. All complexes are strongly colored and display fluorescence in solution associated with the perylene fragment. The influence of the metal fragment on these properties is very small in the isocyanide complexes, but more pronounced in the carbene derivatives, revealing a higher electronic connection between the metal and the PDI group in the carbene-complexes. Stable Langmuir films are formed by CN-PDI, [C6F5-Au-CN-PDI] and [H13C6OC6F4-Au-CN-PDI], in which, remarkably, by varying the compression of the films at the air/water interface it is possible to modulate the molecular arrangement in LS multi-layered films.Ministerio de Economía, Industria y Competitividad ((Project CTQ2014-52796-P)Junta de Castilla y León (programa de apoyo a proyectos de investigación - Ref. VA302U13)Elsevier2017info:eu-repo/semantics/articleapplication/pdfhttps://doi.org/10.1016/j.dyepig.2017.01.057http://uvadoc.uva.es/handle/10324/33434reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://www.sciencedirect.com/science/article/pii/S0143720816309603info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/oai:uvadoc.uva.es:10324/334342026-06-13T12:44:47Z
dc.title.none.fl_str_mv Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
title Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
spellingShingle Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
Domínguez, Cristina
Tinte organometálico
Organometallic dye
title_short Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
title_full Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
title_fullStr Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
title_full_unstemmed Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
title_sort Perylenecarboxydiimide-Gold(I) Organometallic Dyes. Optical Properties and Langmuir Films
dc.creator.none.fl_str_mv Domínguez, Cristina
Baena Alonso, María Jesús
Coco Cea, Silverio
Espinet Rubio, Pablo
author Domínguez, Cristina
author_facet Domínguez, Cristina
Baena Alonso, María Jesús
Coco Cea, Silverio
Espinet Rubio, Pablo
author_role author
author2 Baena Alonso, María Jesús
Coco Cea, Silverio
Espinet Rubio, Pablo
author2_role author
author
author
dc.subject.none.fl_str_mv Tinte organometálico
Organometallic dye
topic Tinte organometálico
Organometallic dye
description Producción Científica
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://doi.org/10.1016/j.dyepig.2017.01.057
http://uvadoc.uva.es/handle/10324/33434
url https://doi.org/10.1016/j.dyepig.2017.01.057
http://uvadoc.uva.es/handle/10324/33434
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://www.sciencedirect.com/science/article/pii/S0143720816309603
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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