Magnetic concentration of allele-specific products from recombinase polymerase amplification

[EN] The studied challenge is the specific detection of low-abundant genomic variants that differ by a single nucleotide from the wild type. The combination of blocked recombinase polymerase amplification (RPA) and selective capture by probes immobilised on magnetic-core particles integrated into a...

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Detalhes bibliográficos
Autores: Martorell-Tejedor, Sara, Tortajada-Genaro, Luis Antonio|||0000-0003-4021-5607, Maquieira, Angel|||0000-0003-4641-4957
Formato: artículo
Fecha de publicación:2019
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/138901
Acesso em linha:https://riunet.upv.es/handle/10251/138901
Access Level:acceso abierto
Palavra-chave:Isothermal amplification
Magnetic beads
In-chip hybridization
DNA genotyping
Optical biosensing
QUIMICA ANALITICA
Descrição
Resumo:[EN] The studied challenge is the specific detection of low-abundant genomic variants that differ by a single nucleotide from the wild type. The combination of blocked recombinase polymerase amplification (RPA) and selective capture by probes immobilised on magnetic-core particles integrated into a flow system is presented. The sensing principle was demonstrated as the effective concentration-detection of the specific generated products was achieved. The analytical performance of resulting assay was successfully compared to PCR-based methods or array formats, providing faster effective detection of the selective products. As proof of concept, the single-nucleotide substitutions of the KRAS gene at codon 12 were studied in chip with parallel microchambers and permanent magnets. The blocked RPA products (generated at 37 degrees C) from tumour biopsies (extracted DNA 4 ng) provided a specific fluorescent bead-line that depends on the present mutation. The results agree with those reported by next-generation sequencing and provide new opportunities for in vitro diagnostic and personalised medicine.