Catalytic Photoinduced Intramolecular Decarboxylative and Desulfonylative sp3Allylation Enabled by Sulfinate Salts
Herein, we describe a catalytic intramolecular decarboxylative/desulfonylative sp3 allylation triggered by sulfinate salts under light irradiation. The reaction is likely enabled by a non-classical, radical-polar crossover reaction, allowing to rapidly and reliably access valuable allyl architecture...
| Autores: | , , , |
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| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2023 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/534683 |
| Acesso em linha: | http://hdl.handle.net/2072/534683 https://doi.org/10.1002/anie.202304084 |
| Access Level: | acceso abierto |
| Palavra-chave: | Química 00 |
| Resumo: | Herein, we describe a catalytic intramolecular decarboxylative/desulfonylative sp3 allylation triggered by sulfinate salts under light irradiation. The reaction is likely enabled by a non-classical, radical-polar crossover reaction, allowing to rapidly and reliably access valuable allyl architectures from readily accessible precursors. The protocol is characterized by its operational simplicity and scalability, employing abundant, commercially available catalysts |
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