Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties

Four new lanthanide-carboxylate coordination polymers of the formula [Ln3L4(phen)4(H2O)4](ClO4)·2H2O, (Ln = Dy (1), Tb (2), Ho (3) and Er (4), L = 2,3-naphthalenedicarboxylate and phen = 1,10-phenanthroline) were solvothermally synthesized. Their structures as well as magnetic and photoluminescent p...

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Detalhes bibliográficos
Autores: Hu, Min, Zhao, Hui, Sañudo Zotes, Eva Carolina, Chen, Min
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/154127
Acesso em linha:https://hdl.handle.net/2445/154127
Access Level:acceso abierto
Palavra-chave:Luminescència
Propietats magnètiques
Luminescence
Magnetic properties
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spelling Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic propertiesHu, MinZhao, HuiSañudo Zotes, Eva CarolinaChen, MinLuminescènciaPropietats magnètiquesLuminescenceMagnetic propertiesFour new lanthanide-carboxylate coordination polymers of the formula [Ln3L4(phen)4(H2O)4](ClO4)·2H2O, (Ln = Dy (1), Tb (2), Ho (3) and Er (4), L = 2,3-naphthalenedicarboxylate and phen = 1,10-phenanthroline) were solvothermally synthesized. Their structures as well as magnetic and photoluminescent properties were completely investigated. Complexes 1-4 are isostructural and exhibit 1D ribbon-like chains with envelope-like sixteen-membered rings. The DyIII and TbIII complexes show the corresponding characteristic luminescence in the visible region and the ErIII complex shows luminescence in the near-infrared region upon excitation with UV rays. Studies on the magnetic properties are reported. The Dy(III) analog complex 1 exhibits slow magnetic relaxation and could be a new example of a Dy(III) SMM (single molecule magnet).Elsevier Ltd2020202020152020info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion6 p.application/pdfhttps://hdl.handle.net/2445/154127Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésVersió postprint del document publicat a: https://doi.org/10.1016/j.poly.2015.08.030Polyhedron, 2015, vol. 101, p. 270-275https://doi.org/10.1016/j.poly.2015.08.030cc-by-nc-nd (c) Elsevier Ltd, 2015http://creativecommons.org/licenses/by-nc-nd/3.0/esinfo:eu-repo/semantics/openAccessoai:recercat.cat:2445/1541272026-05-29T05:05:01Z
dc.title.none.fl_str_mv Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
title Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
spellingShingle Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
Hu, Min
Luminescència
Propietats magnètiques
Luminescence
Magnetic properties
title_short Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
title_full Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
title_fullStr Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
title_full_unstemmed Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
title_sort Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties
dc.creator.none.fl_str_mv Hu, Min
Zhao, Hui
Sañudo Zotes, Eva Carolina
Chen, Min
author Hu, Min
author_facet Hu, Min
Zhao, Hui
Sañudo Zotes, Eva Carolina
Chen, Min
author_role author
author2 Zhao, Hui
Sañudo Zotes, Eva Carolina
Chen, Min
author2_role author
author
author
dc.subject.none.fl_str_mv Luminescència
Propietats magnètiques
Luminescence
Magnetic properties
topic Luminescència
Propietats magnètiques
Luminescence
Magnetic properties
description Four new lanthanide-carboxylate coordination polymers of the formula [Ln3L4(phen)4(H2O)4](ClO4)·2H2O, (Ln = Dy (1), Tb (2), Ho (3) and Er (4), L = 2,3-naphthalenedicarboxylate and phen = 1,10-phenanthroline) were solvothermally synthesized. Their structures as well as magnetic and photoluminescent properties were completely investigated. Complexes 1-4 are isostructural and exhibit 1D ribbon-like chains with envelope-like sixteen-membered rings. The DyIII and TbIII complexes show the corresponding characteristic luminescence in the visible region and the ErIII complex shows luminescence in the near-infrared region upon excitation with UV rays. Studies on the magnetic properties are reported. The Dy(III) analog complex 1 exhibits slow magnetic relaxation and could be a new example of a Dy(III) SMM (single molecule magnet).
publishDate 2015
dc.date.none.fl_str_mv 2015
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/154127
url https://hdl.handle.net/2445/154127
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2015.08.030
Polyhedron, 2015, vol. 101, p. 270-275
https://doi.org/10.1016/j.poly.2015.08.030
dc.rights.none.fl_str_mv cc-by-nc-nd (c) Elsevier Ltd, 2015
http://creativecommons.org/licenses/by-nc-nd/3.0/es
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by-nc-nd (c) Elsevier Ltd, 2015
http://creativecommons.org/licenses/by-nc-nd/3.0/es
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 6 p.
application/pdf
dc.publisher.none.fl_str_mv Elsevier Ltd
publisher.none.fl_str_mv Elsevier Ltd
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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