Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex

The transition metal catalyzed dehydrogenation of alcohols to carboxylate salts and H2 is an attractive tool due to their potential use as LOHCs (Liquid Organic Hydrogen Carriers). Still, most current methods encompass harsh conditions and two steps synthesis. Herein, we describe an efficient ruthen...

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Detalles Bibliográficos
Autores: Ibáñez-Ibáñez, Laura, Guisado-Barrios, Gregorio, Mata, José A.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Universidad de Zaragoza
Repositorio:Zaguán. Repositorio Digital de la Universidad de Zaragoza
OAI Identifier:oai:zaguan.unizar.es:160866
Acceso en línea:http://zaguan.unizar.es/record/160866
Access Level:acceso abierto
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spelling Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complexIbáñez-Ibáñez, LauraGuisado-Barrios, GregorioMata, José A.The transition metal catalyzed dehydrogenation of alcohols to carboxylate salts and H2 is an attractive tool due to their potential use as LOHCs (Liquid Organic Hydrogen Carriers). Still, most current methods encompass harsh conditions and two steps synthesis. Herein, we describe an efficient ruthenium(II) catalyzed hydrogen production from benzylic alcohols to the corresponding carboxylate derivatives assisted by visible light. Our photocatalytic system comprises a standalone N-heterocyclic carbene based piano stool ruthenium complex playing a dual role, harvesting visible-light and enabling H2 generation under mild conditions in aqueous media.2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://zaguan.unizar.es/record/160866reponame:Zaguán. Repositorio Digital de la Universidad de Zaragozainstname:Universidad de ZaragozaInglésinfo:eu-repo/grantAgreement/ES/AEI/PID2021-122900NB-I00info:eu-repo/grantAgreement/ES/AEI/PID2021-126071OB-C22info:eu-repo/grantAgreement/ES/DGA/E50-23Rinfo:eu-repo/grantAgreement/ES/MICINN/RED2022-134074-Tinfo:eu-repo/grantAgreement/ES/MIU/FPU20-04385info:eu-repo/semantics/openAccessoai:zaguan.unizar.es:1608662026-05-29T13:59:51Z
dc.title.none.fl_str_mv Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
title Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
spellingShingle Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
Ibáñez-Ibáñez, Laura
title_short Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
title_full Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
title_fullStr Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
title_full_unstemmed Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
title_sort Photodehydrogenation of alcohols catalysed by a single ruthenium N-Heterocyclic carbene complex
dc.creator.none.fl_str_mv Ibáñez-Ibáñez, Laura
Guisado-Barrios, Gregorio
Mata, José A.
author Ibáñez-Ibáñez, Laura
author_facet Ibáñez-Ibáñez, Laura
Guisado-Barrios, Gregorio
Mata, José A.
author_role author
author2 Guisado-Barrios, Gregorio
Mata, José A.
author2_role author
author
description The transition metal catalyzed dehydrogenation of alcohols to carboxylate salts and H2 is an attractive tool due to their potential use as LOHCs (Liquid Organic Hydrogen Carriers). Still, most current methods encompass harsh conditions and two steps synthesis. Herein, we describe an efficient ruthenium(II) catalyzed hydrogen production from benzylic alcohols to the corresponding carboxylate derivatives assisted by visible light. Our photocatalytic system comprises a standalone N-heterocyclic carbene based piano stool ruthenium complex playing a dual role, harvesting visible-light and enabling H2 generation under mild conditions in aqueous media.
publishDate 2025
dc.date.none.fl_str_mv 2025
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info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://zaguan.unizar.es/record/160866
url http://zaguan.unizar.es/record/160866
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
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info:eu-repo/grantAgreement/ES/DGA/E50-23R
info:eu-repo/grantAgreement/ES/MICINN/RED2022-134074-T
info:eu-repo/grantAgreement/ES/MIU/FPU20-04385
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instname:Universidad de Zaragoza
instname_str Universidad de Zaragoza
reponame_str Zaguán. Repositorio Digital de la Universidad de Zaragoza
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