Thermally reduced graphite oxide as positive electrode in Vanadium Redox Flow Batteries
[EN] Two graphene-like materials, obtained by thermal exfoliation and reduction of a graphite oxide at 700 and 1000 °C, were studied as active electrodes in the positive half-cell of a Vanadium Redox Flow Battery (VRFB). In particular, that obtained at 1000 °C exhibited an outstanding electrochemica...
| Autores: | , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2012 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/88991 |
| Acceso en línea: | http://hdl.handle.net/10261/88991 |
| Access Level: | acceso abierto |
| Palabra clave: | Graphite oxide VRFB |
| Sumario: | [EN] Two graphene-like materials, obtained by thermal exfoliation and reduction of a graphite oxide at 700 and 1000 °C, were studied as active electrodes in the positive half-cell of a Vanadium Redox Flow Battery (VRFB). In particular, that obtained at 1000 °C exhibited an outstanding electrochemical performance in terms of peak current densities (30.54 and 30.05 mA cm−2 for the anodic and cathodic peaks at 1 mV s−1, respectively) and reversibility (ΔEp = 0.07 V). This excellent behavior is attributed to the restoration of sp2 domains after thermal treatment, which implies the production of a graphene-like material with a high electrical conductivity and accessible surface area. Moreover, the residual functional groups, –OH, act as active sites towards the vanadium redox reactions. This represents a significant step forward in the development of highly effective VRFB electrode materials. |
|---|