Graphenes as Efficient Metal-Free Fenton Catalysts

Reduced graphene oxide exhibits high activity as Fenton catalyst with HO. radical generation efficiency over 82 % and turnover numbers of 4540 and 15023 for phenol degradation and H2O2 consumption, respectively. These values compare favorably with those achieved with transition metals, showing the p...

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Detalles Bibliográficos
Autores: Espinosa, Juan C., Navalõn, Sergio, Primo, Ana, Moral, Mónica, Fernández Sanz, Javier, Álvaro, Mercedes, García, Hermenegildo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/133450
Acceso en línea:https://hdl.handle.net/11441/133450
https://doi.org/10.1002/chem.201501533
Access Level:acceso abierto
Palabra clave:Carbon
Fenton reaction
Graphene
Heterogeneous catalysis
Radicals
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spelling Graphenes as Efficient Metal-Free Fenton CatalystsEspinosa, Juan C.Navalõn, SergioPrimo, AnaMoral, MónicaFernández Sanz, JavierÁlvaro, MercedesGarcía, HermenegildoCarbonFenton reactionGrapheneHeterogeneous catalysisRadicalsReduced graphene oxide exhibits high activity as Fenton catalyst with HO. radical generation efficiency over 82 % and turnover numbers of 4540 and 15023 for phenol degradation and H2O2 consumption, respectively. These values compare favorably with those achieved with transition metals, showing the potential of carbocatalysts for the Fenton reaction.Generalitat Valenciana GV/2013/040Ministerio de Economía y Competitividad CTQ2012-32315Wiley-BlackwellQuímica FísicaGeneralitat ValencianaMinisterio de Economía y Competitividad (MINECO). España2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/133450https://doi.org/10.1002/chem.201501533reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésChemistry - A European Journal, 21 (34), 11966-11971.GV/2013/040CTQ2012-32315https://doi.org/10.1002/chem.201501533info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1334502026-06-17T12:51:07Z
dc.title.none.fl_str_mv Graphenes as Efficient Metal-Free Fenton Catalysts
title Graphenes as Efficient Metal-Free Fenton Catalysts
spellingShingle Graphenes as Efficient Metal-Free Fenton Catalysts
Espinosa, Juan C.
Carbon
Fenton reaction
Graphene
Heterogeneous catalysis
Radicals
title_short Graphenes as Efficient Metal-Free Fenton Catalysts
title_full Graphenes as Efficient Metal-Free Fenton Catalysts
title_fullStr Graphenes as Efficient Metal-Free Fenton Catalysts
title_full_unstemmed Graphenes as Efficient Metal-Free Fenton Catalysts
title_sort Graphenes as Efficient Metal-Free Fenton Catalysts
dc.creator.none.fl_str_mv Espinosa, Juan C.
Navalõn, Sergio
Primo, Ana
Moral, Mónica
Fernández Sanz, Javier
Álvaro, Mercedes
García, Hermenegildo
author Espinosa, Juan C.
author_facet Espinosa, Juan C.
Navalõn, Sergio
Primo, Ana
Moral, Mónica
Fernández Sanz, Javier
Álvaro, Mercedes
García, Hermenegildo
author_role author
author2 Navalõn, Sergio
Primo, Ana
Moral, Mónica
Fernández Sanz, Javier
Álvaro, Mercedes
García, Hermenegildo
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Química Física
Generalitat Valenciana
Ministerio de Economía y Competitividad (MINECO). España
dc.subject.none.fl_str_mv Carbon
Fenton reaction
Graphene
Heterogeneous catalysis
Radicals
topic Carbon
Fenton reaction
Graphene
Heterogeneous catalysis
Radicals
description Reduced graphene oxide exhibits high activity as Fenton catalyst with HO. radical generation efficiency over 82 % and turnover numbers of 4540 and 15023 for phenol degradation and H2O2 consumption, respectively. These values compare favorably with those achieved with transition metals, showing the potential of carbocatalysts for the Fenton reaction.
publishDate 2015
dc.date.none.fl_str_mv 2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/133450
https://doi.org/10.1002/chem.201501533
url https://hdl.handle.net/11441/133450
https://doi.org/10.1002/chem.201501533
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Chemistry - A European Journal, 21 (34), 11966-11971.
GV/2013/040
CTQ2012-32315
https://doi.org/10.1002/chem.201501533
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley-Blackwell
publisher.none.fl_str_mv Wiley-Blackwell
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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