Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvate
In the title compound, [Ir(C15H22BN6)(C8H7O)Cl]·CHCl3, the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir Ccarbene bond is strong and short and exerts a notable effect on the trans-I...
| Autores: | , , |
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| Tipo de documento: | artigo |
| Estado: | Versão publicada |
| Data de publicação: | 2013 |
| País: | España |
| Recursos: | Universidad de Sevilla (US) |
| Repositório: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/57482 |
| Acesso em linha: | http://hdl.handle.net/11441/57482 |
| Access Level: | Acceso aberto |
| Resumo: | In the title compound, [Ir(C15H22BN6)(C8H7O)Cl]·CHCl3, the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir Ccarbene bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 A˚ longer than the two other Ir—N bonds. The chloroform solvent molecule is anchored via a weak C—H·· ·Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C—H·· ·Cl hydrogen bonds, as well as weak Cl·· ·Cl [3.498 (2) A˚ ] and Cl·· ·JT [3.360 (4) A˚ ] inter- actions. A weak intramolecular C—H·· ·O hydrogen bond is also observed |
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