Albero: An alternative natural material for solar energy storage by the calcium-looping process

Large-scale thermochemical energy storage (TCES) is gaining relevance as an alternative to current thermal energy storage systems in Concentrated Solar Power plants. Among the different systems, the reversible reaction between CaO and CO2 stands out due to the wide availability and low cost of the r...

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Autores: Moreno, Virginia, Arcenegui-Troya, Juan, Sánchez-Jiménez, Pedro Enrique, Perejón, Antonio, Chacartegui, Ricardo, Valverde, José Manuel, Pérez-Maqueda, Luis Allan
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad Loyola Andalucía
Repositorio:Brújula
OAI Identifier:oai:repositorio.uloyola.es:20.500.12412/6390
Acceso en línea:https://hdl.handle.net/20.500.12412/6390
Access Level:acceso abierto
Palabra clave:Albero
Calcium-Looping
Limestone
Solar absorptance
Thermochemical energy storage
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spelling Albero: An alternative natural material for solar energy storage by the calcium-looping processMoreno, VirginiaArcenegui-Troya, JuanSánchez-Jiménez, Pedro EnriquePerejón, AntonioChacartegui, RicardoValverde, José ManuelPérez-Maqueda, Luis AllanAlberoCalcium-LoopingLimestoneSolar absorptanceThermochemical energy storageLarge-scale thermochemical energy storage (TCES) is gaining relevance as an alternative to current thermal energy storage systems in Concentrated Solar Power plants. Among the different systems, the reversible reaction between CaO and CO2 stands out due to the wide availability and low cost of the raw material: limestone. Direct solar absorption of the storage media would improve the efficiency of solar-to-thermal energy storage due to reduced thermal transfer barriers, but the solar optical absorption of CaCO3 is poor. In this work, we propose the use of a Ca-rich calcarenite sedimentary rock so-called albero as an alternative to limestone. We demonstrate that this reddish material exhibits an average solar absorptance that is approximately ten times larger than limestone. Moreover, the multicycle carbonation/calcination performance under different experimental conditions has been studied by thermogravimetry, and similar values to those exhibited for limestone have been obtained. Besides, the material is cheap (6 €/ton), and simulations showed that the use of this material would significantly improve the overall CaL-CSP efficiency at the industrial level.2022info:eu-repo/semantics/articlehttps://hdl.handle.net/20.500.12412/6390reponame:Brújulainstname:Universidad Loyola AndalucíaInglésP18-FR-1087, US-1262507; 201960E092, 202060I004; MCIN/AEI /10.13039/501100011033, PDC2021-121552-C21info:eu-repo/semantics/openAccessoai:repositorio.uloyola.es:20.500.12412/63902026-06-24T12:48:37Z
dc.title.none.fl_str_mv Albero: An alternative natural material for solar energy storage by the calcium-looping process
title Albero: An alternative natural material for solar energy storage by the calcium-looping process
spellingShingle Albero: An alternative natural material for solar energy storage by the calcium-looping process
Moreno, Virginia
Albero
Calcium-Looping
Limestone
Solar absorptance
Thermochemical energy storage
title_short Albero: An alternative natural material for solar energy storage by the calcium-looping process
title_full Albero: An alternative natural material for solar energy storage by the calcium-looping process
title_fullStr Albero: An alternative natural material for solar energy storage by the calcium-looping process
title_full_unstemmed Albero: An alternative natural material for solar energy storage by the calcium-looping process
title_sort Albero: An alternative natural material for solar energy storage by the calcium-looping process
dc.creator.none.fl_str_mv Moreno, Virginia
Arcenegui-Troya, Juan
Sánchez-Jiménez, Pedro Enrique
Perejón, Antonio
Chacartegui, Ricardo
Valverde, José Manuel
Pérez-Maqueda, Luis Allan
author Moreno, Virginia
author_facet Moreno, Virginia
Arcenegui-Troya, Juan
Sánchez-Jiménez, Pedro Enrique
Perejón, Antonio
Chacartegui, Ricardo
Valverde, José Manuel
Pérez-Maqueda, Luis Allan
author_role author
author2 Arcenegui-Troya, Juan
Sánchez-Jiménez, Pedro Enrique
Perejón, Antonio
Chacartegui, Ricardo
Valverde, José Manuel
Pérez-Maqueda, Luis Allan
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Albero
Calcium-Looping
Limestone
Solar absorptance
Thermochemical energy storage
topic Albero
Calcium-Looping
Limestone
Solar absorptance
Thermochemical energy storage
description Large-scale thermochemical energy storage (TCES) is gaining relevance as an alternative to current thermal energy storage systems in Concentrated Solar Power plants. Among the different systems, the reversible reaction between CaO and CO2 stands out due to the wide availability and low cost of the raw material: limestone. Direct solar absorption of the storage media would improve the efficiency of solar-to-thermal energy storage due to reduced thermal transfer barriers, but the solar optical absorption of CaCO3 is poor. In this work, we propose the use of a Ca-rich calcarenite sedimentary rock so-called albero as an alternative to limestone. We demonstrate that this reddish material exhibits an average solar absorptance that is approximately ten times larger than limestone. Moreover, the multicycle carbonation/calcination performance under different experimental conditions has been studied by thermogravimetry, and similar values to those exhibited for limestone have been obtained. Besides, the material is cheap (6 €/ton), and simulations showed that the use of this material would significantly improve the overall CaL-CSP efficiency at the industrial level.
publishDate 2022
dc.date.none.fl_str_mv 2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.12412/6390
url https://hdl.handle.net/20.500.12412/6390
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv P18-FR-1087, US-1262507; 201960E092, 202060I004; MCIN/AEI /10.13039/501100011033, PDC2021-121552-C21
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Brújula
instname:Universidad Loyola Andalucía
instname_str Universidad Loyola Andalucía
reponame_str Brújula
collection Brújula
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155