Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts

14 figures, 6 tables.

Detalles Bibliográficos
Autores: Frecha, Esther, Remón, Javier, Torres Gamarra, Daniel, Suelves Laiglesia, Isabel, Pinilla Ibarz, José Luis
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/287706
Acceso en línea:http://hdl.handle.net/10261/287706
Access Level:acceso abierto
Palabra clave:Cellulose
Hydrolytic hydrogenation
Carbon supported catalysts
Nickel
Sorbitol
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
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spelling Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalystsFrecha, EstherRemón, JavierTorres Gamarra, DanielSuelves Laiglesia, IsabelPinilla Ibarz, José LuisCelluloseHydrolytic hydrogenationCarbon supported catalystsNickelSorbitolhttp://metadata.un.org/sdg/7Ensure access to affordable, reliable, sustainable and modern energy for allEnsure sustainable consumption and production patterns14 figures, 6 tables.The synthesis of sorbitol from cellulose over Ni catalysts is a promising valorisation route in the biorefinery scenario, applying relatively simple preparation methods and earth-abundant metals. The overall selectivity, however, depends on the kinetic control of a complex reaction network, involving the hydrolysis of cellulose to monosaccharides via cello-oligomers, glucose hydrogenation into sorbitol and hydrogenolysis side-reactions of sugars and sorbitol to low molecular weight polyols. Therein, subtle changes in the catalyst composition and process conditions might have a strong impact on the final product distribution. Driven by these challenges, this work first-time provides novel insights into the hydrothermal hydrogenation of cellulose over a carbon nanofibre supported Ni catalyst (Ni/CNF). Firstly, the impact of the duration of a ball-milling pre-treatment step and the influences of the hydrothermal time and temperature were thoroughly analysed. The experimental results obtained highlighted the importance of process control to promote the first transformation of cellulose to glucose and its subsequent hydrogenation to sorbitol to minimise the extension of side reactions. Finally, an additional study was conducted to palliate the recalcitrant nature of cellulose by decreasing mass transfer limitations to a minimum extent. This was achieved by including an additional mix-milling of the amorphous cellulose produced in the first pre-treatment with the catalyst and increasing the H2 pressure of the hydrothermal hydrogenation process. This allowed attaining a sorbitol yield as high as 62% at 190 ºC using an initial H2 pressure of 8 MPa for 26 h, which is one of the best results reported in the literature.The authors are grateful for the financial support from the Spanish Ministry of Economy and Competitiveness (MINECO, Project ENE2017-83854-R) and the I+D+i project PID2020-115053RB-I00, funded by MCIN/ AEI/10.13039/501100011033. J.R. and D.T. are grateful to the Spanish Ministry of Science, Innovation and Universities for the Juan de la Cierva Incorporación (JdC-I) fellowships (Grant Numbers: IJC2018-037110-I and IJC2020-045553-I, respectively) awarded.Peer reviewedElsevier BVMinisterio de Economía, Industria y Competitividad (España)Ministerio de Ciencia e Innovación (España)Agencia Estatal de Investigación (España)European CommissionMinisterio de Ciencia, Innovación y Universidades (España)Remón, Javier [0000-0003-3315-5933]Torres Gamarra, Daniel [0000-0002-7843-6141]Suelves Laiglesia, Isabel [0000-0001-8437-2204]Pinilla Ibarz, José Luis [0000-0002-8304-9656]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202320232023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/287706reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-83854-Rinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115053RB-I00http://dx.doi.org/10.1016/j.cattod.2023.01.009Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2877062026-05-22T06:33:51Z
dc.title.none.fl_str_mv Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
title Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
spellingShingle Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
Frecha, Esther
Cellulose
Hydrolytic hydrogenation
Carbon supported catalysts
Nickel
Sorbitol
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
title_short Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
title_full Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
title_fullStr Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
title_full_unstemmed Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
title_sort Optimisation of the processing conditions of hydrolytic hydrogenation of cellulose using carbon nanofiber supported Ni catalysts
dc.creator.none.fl_str_mv Frecha, Esther
Remón, Javier
Torres Gamarra, Daniel
Suelves Laiglesia, Isabel
Pinilla Ibarz, José Luis
author Frecha, Esther
author_facet Frecha, Esther
Remón, Javier
Torres Gamarra, Daniel
Suelves Laiglesia, Isabel
Pinilla Ibarz, José Luis
author_role author
author2 Remón, Javier
Torres Gamarra, Daniel
Suelves Laiglesia, Isabel
Pinilla Ibarz, José Luis
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía, Industria y Competitividad (España)
Ministerio de Ciencia e Innovación (España)
Agencia Estatal de Investigación (España)
European Commission
Ministerio de Ciencia, Innovación y Universidades (España)
Remón, Javier [0000-0003-3315-5933]
Torres Gamarra, Daniel [0000-0002-7843-6141]
Suelves Laiglesia, Isabel [0000-0001-8437-2204]
Pinilla Ibarz, José Luis [0000-0002-8304-9656]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Cellulose
Hydrolytic hydrogenation
Carbon supported catalysts
Nickel
Sorbitol
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
topic Cellulose
Hydrolytic hydrogenation
Carbon supported catalysts
Nickel
Sorbitol
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
description 14 figures, 6 tables.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/287706
url http://hdl.handle.net/10261/287706
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-83854-R
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115053RB-I00
http://dx.doi.org/10.1016/j.cattod.2023.01.009
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier BV
publisher.none.fl_str_mv Elsevier BV
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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