Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste

This study analyses how a Mg-Al-Hydrotalcite with carbonate in the interlayer influences the hydration of mortar allowing the management of lead waste (solid or liquid) in a cement-based material. First, the compatibility of hydrotalcite with the cementitious matrix was studied through heat of hydra...

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Autores: Lozano-Lunar, A. (Angélica)|||/items/80d0f634-2b74-459b-8c53-20ce436c037a, Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204, Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54, Jiménez, J.R. (José Ramón)|||/items/2ef28b9c-a6ea-4f2b-bde2-49935d266102, Fernández-Rodríguez, J.M. (José María)|||/items/4c3c942b-7a26-4807-94e4-3c607039d0de
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad de Navarra
Repositorio:Dadun. Depósito Académico Digital de la Universidad de Navarra
Idioma:inglés
OAI Identifier:oai:dadun.unav.edu:10171/62121
Acceso en línea:https://hdl.handle.net/10171/62121
Access Level:acceso abierto
Palabra clave:Hydrotalcite
Lead
Mortar
Calorimetry
Leaching
Waste management
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spelling Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead wasteLozano-Lunar, A. (Angélica)|||/items/80d0f634-2b74-459b-8c53-20ce436c037aAlvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54Jiménez, J.R. (José Ramón)|||/items/2ef28b9c-a6ea-4f2b-bde2-49935d266102Fernández-Rodríguez, J.M. (José María)|||/items/4c3c942b-7a26-4807-94e4-3c607039d0deHydrotalciteLeadMortarCalorimetryLeachingWaste managementThis study analyses how a Mg-Al-Hydrotalcite with carbonate in the interlayer influences the hydration of mortar allowing the management of lead waste (solid or liquid) in a cement-based material. First, the compatibility of hydrotalcite with the cementitious matrix was studied through heat of hydration, workability, consistency, compressive strength and mineralogical phase formation. The changes produced by the incorporation of hydrotalcite were not drastic and the compatibility with the cement was verified. Lead was added in oxide and nitrate form to mortar with or without hydrotalcite and the same properties were evaluated, including a leaching test. The incorporation of lead delayed the hydration, this effect being increased by the hydrotalcite, which happened in the first instants of hydration. The addition of hydrotalcite counteracted the negative effect of lead in compressive strength values. The interaction between the hydrotalcite and the lead waste was favoured by the formation of plumbites under the pH conditions of cement hydration. Consequently, this interaction would seem to be superficial. The lead leaching decreased to values included in the "Non-Hazardous" limit of the environmental classification, very close to "Inert". All mortars were produced by two mixing procedures to establish differences. When hydrotalcite was included, the compressive strength was higher in the second procedure and lead leaching showed better behaviour in the first procedure.Dadun. Depósito Académico Digital Universidad de Navarra20212021-09-3020212021-01-0120212021-01-01journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10171/62121reponame:Dadun. Depósito Académico Digital de la Universidad de Navarrainstname:Universidad de NavarraInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:dadun.unav.edu:10171/621212026-06-21T12:47:57Z
dc.title.none.fl_str_mv Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
title Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
spellingShingle Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
Lozano-Lunar, A. (Angélica)|||/items/80d0f634-2b74-459b-8c53-20ce436c037a
Hydrotalcite
Lead
Mortar
Calorimetry
Leaching
Waste management
title_short Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
title_full Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
title_fullStr Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
title_full_unstemmed Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
title_sort Optimisation of mortar with Mg-Al-Hydrotalcite as sustainable management strategy lead waste
dc.creator.none.fl_str_mv Lozano-Lunar, A. (Angélica)|||/items/80d0f634-2b74-459b-8c53-20ce436c037a
Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54
Jiménez, J.R. (José Ramón)|||/items/2ef28b9c-a6ea-4f2b-bde2-49935d266102
Fernández-Rodríguez, J.M. (José María)|||/items/4c3c942b-7a26-4807-94e4-3c607039d0de
author Lozano-Lunar, A. (Angélica)|||/items/80d0f634-2b74-459b-8c53-20ce436c037a
author_facet Lozano-Lunar, A. (Angélica)|||/items/80d0f634-2b74-459b-8c53-20ce436c037a
Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54
Jiménez, J.R. (José Ramón)|||/items/2ef28b9c-a6ea-4f2b-bde2-49935d266102
Fernández-Rodríguez, J.M. (José María)|||/items/4c3c942b-7a26-4807-94e4-3c607039d0de
author_role author
author2 Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54
Jiménez, J.R. (José Ramón)|||/items/2ef28b9c-a6ea-4f2b-bde2-49935d266102
Fernández-Rodríguez, J.M. (José María)|||/items/4c3c942b-7a26-4807-94e4-3c607039d0de
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Dadun. Depósito Académico Digital Universidad de Navarra
dc.subject.none.fl_str_mv Hydrotalcite
Lead
Mortar
Calorimetry
Leaching
Waste management
topic Hydrotalcite
Lead
Mortar
Calorimetry
Leaching
Waste management
description This study analyses how a Mg-Al-Hydrotalcite with carbonate in the interlayer influences the hydration of mortar allowing the management of lead waste (solid or liquid) in a cement-based material. First, the compatibility of hydrotalcite with the cementitious matrix was studied through heat of hydration, workability, consistency, compressive strength and mineralogical phase formation. The changes produced by the incorporation of hydrotalcite were not drastic and the compatibility with the cement was verified. Lead was added in oxide and nitrate form to mortar with or without hydrotalcite and the same properties were evaluated, including a leaching test. The incorporation of lead delayed the hydration, this effect being increased by the hydrotalcite, which happened in the first instants of hydration. The addition of hydrotalcite counteracted the negative effect of lead in compressive strength values. The interaction between the hydrotalcite and the lead waste was favoured by the formation of plumbites under the pH conditions of cement hydration. Consequently, this interaction would seem to be superficial. The lead leaching decreased to values included in the "Non-Hazardous" limit of the environmental classification, very close to "Inert". All mortars were produced by two mixing procedures to establish differences. When hydrotalcite was included, the compressive strength was higher in the second procedure and lead leaching showed better behaviour in the first procedure.
publishDate 2021
dc.date.none.fl_str_mv 2021
2021-09-30
2021
2021-01-01
2021
2021-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10171/62121
url https://hdl.handle.net/10171/62121
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dadun. Depósito Académico Digital de la Universidad de Navarra
instname:Universidad de Navarra
instname_str Universidad de Navarra
reponame_str Dadun. Depósito Académico Digital de la Universidad de Navarra
collection Dadun. Depósito Académico Digital de la Universidad de Navarra
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