Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]

In the title compound, {[Ni(C10H8N4)2(H2O)2]I2·2C2H5OH}n, the complex shows an octa­hedral environment of the Ni2+ cation in which it is located on a centre of symmetry, linked to two water mol­ecules and the pyridine-N atoms of four 4,4'-(diazenediyl)dipyridine ligands bridging Ni2+ cations al...

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Detalles Bibliográficos
Autores: Perles Hernáez, Josefina, Cortijo Montes, Miguel, Herrero Domínguez, Santiago
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/93114
Acceso en línea:https://hdl.handle.net/20.500.14352/93114
Access Level:acceso abierto
Palabra clave:546
Crystal structure
Nickel coordination compound
Bidimensional MOF
Cationic network.
Química
2303 Química Inorgánica
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oai_identifier_str oai:docta.ucm.es:20.500.14352/93114
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network_name_str España
repository_id_str
spelling Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]Perles Hernáez, JosefinaCortijo Montes, MiguelHerrero Domínguez, Santiago546Crystal structureNickel coordination compoundBidimensional MOFCationic network.Química2303 Química InorgánicaIn the title compound, {[Ni(C10H8N4)2(H2O)2]I2·2C2H5OH}n, the complex shows an octa­hedral environment of the Ni2+ cation in which it is located on a centre of symmetry, linked to two water mol­ecules and the pyridine-N atoms of four 4,4'-(diazenediyl)dipyridine ligands bridging Ni2+ cations along the b- and c-axis directions, giving rise to a two-dimensional arrangement. The Ni-N bond lengths are in the range 2.109 (4)-2.186 (3) Å and the Ni-O bond length is 2.080 (3) Å. The 4,4'-(diazenedi­yl)dipyridine ligand lies on an inversion centre. An O-H...O hydrogen-bond inter­action is observed between water and ethanol mol­ecules. The I- ions can be regarded as free anions in the crystal lattice.Crystallographic CommunicationsUniversidad Complutense de Madrid20142014-01-0120142014-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/93114reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/931142026-06-02T12:44:21Z
dc.title.none.fl_str_mv Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
title Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
spellingShingle Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
Perles Hernáez, Josefina
546
Crystal structure
Nickel coordination compound
Bidimensional MOF
Cationic network.
Química
2303 Química Inorgánica
title_short Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
title_full Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
title_fullStr Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
title_full_unstemmed Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
title_sort Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
dc.creator.none.fl_str_mv Perles Hernáez, Josefina
Cortijo Montes, Miguel
Herrero Domínguez, Santiago
author Perles Hernáez, Josefina
author_facet Perles Hernáez, Josefina
Cortijo Montes, Miguel
Herrero Domínguez, Santiago
author_role author
author2 Cortijo Montes, Miguel
Herrero Domínguez, Santiago
author2_role author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 546
Crystal structure
Nickel coordination compound
Bidimensional MOF
Cationic network.
Química
2303 Química Inorgánica
topic 546
Crystal structure
Nickel coordination compound
Bidimensional MOF
Cationic network.
Química
2303 Química Inorgánica
description In the title compound, {[Ni(C10H8N4)2(H2O)2]I2·2C2H5OH}n, the complex shows an octa­hedral environment of the Ni2+ cation in which it is located on a centre of symmetry, linked to two water mol­ecules and the pyridine-N atoms of four 4,4'-(diazenediyl)dipyridine ligands bridging Ni2+ cations along the b- and c-axis directions, giving rise to a two-dimensional arrangement. The Ni-N bond lengths are in the range 2.109 (4)-2.186 (3) Å and the Ni-O bond length is 2.080 (3) Å. The 4,4'-(diazenedi­yl)dipyridine ligand lies on an inversion centre. An O-H...O hydrogen-bond inter­action is observed between water and ethanol mol­ecules. The I- ions can be regarded as free anions in the crystal lattice.
publishDate 2014
dc.date.none.fl_str_mv 2014
2014-01-01
2014
2014-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/93114
url https://hdl.handle.net/20.500.14352/93114
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Crystallographic Communications
publisher.none.fl_str_mv Crystallographic Communications
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,198674

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