Graphitization: Microstructural and microtextural transformations of residual char from international coal combustion ash

Natural graphite is a critical raw material and its substitution in some applications will contribute to reduce its supply risk. Coal ash, which is still produced in high amounts, contains a carbonaceous solid residue (char) that may be a substitute of natural graphite. For this purpose, char may be...

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Detalles Bibliográficos
Autores: Santos, Ana Cláudia, Badenhorst, Charlotte, Białecka, Barbara, Cameán Martínez, Ignacio, Guedes, Alexandra, Moreira, Karen, Predeanu, Georgeta, Suárez Ruiz, Isabel, Wagner, Nicola, Valentim, Bruno
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/374010
Acceso en línea:http://hdl.handle.net/10261/374010
https://api.elsevier.com/content/abstract/scopus_id/85186724512
Access Level:acceso abierto
Palabra clave:Ultimate analysis
Coal fly ash
Electron microscopy
Graphite
Raman microspectroscopy
Reflectance Indicating Surface (RIS) parameters
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Descripción
Sumario:Natural graphite is a critical raw material and its substitution in some applications will contribute to reduce its supply risk. Coal ash, which is still produced in high amounts, contains a carbonaceous solid residue (char) that may be a substitute of natural graphite. For this purpose, char may be graphitized and used in electrocatalysis reactions, however char properties depend on coal rank, composition and combustion conditions that affect the graphitization process. Research on industrial coal char graphitization is limited, resulting in restricted comprehension of the contributing factors. In order to provide novel insights, industrial residual chars (derived from Poland, Portugal, Romania and South Africa) subjected to high-temperature treatments (carbonization at 1000 °C followed by treatment at 2600 °C under environmental pressure) were examined regarding their microstructural and microtextural transformations. The samples were studied by focussing on its heterogeneity, namely its specific properties