Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules

The work presented herein reports on the synthesis, structural and physico-chemical characterization, luminescence properties and luminescent sensing activity of a family of isostructural coordination polymers (CPs) with the general formula [Ln(μ-5Meip)(DMF)] (where Ln(III) = Sm (1), Eu (2), Gd (3),...

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Authors: Pajuelo-Corral, Oier, Razquin-Bobillo, Laura, Rojas, Sara, García, José A., Choquesillo-Lazarte, Duane, Salinas-Castillo, Alfonso, Hernández, Ricardo, Rodríguez-Diéguez, Antonio, Cepeda, Javier
Format: article
Status:Published version
Publication Date:2022
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/357061
Online Access:http://hdl.handle.net/10261/357061
Access Level:Open access
Keyword:Coordination polymers
Lanthanide
5-methylisophthalate
Photoluminescence properties
TDDFT calculations
CIS INDO/S calculations
Charge transfers calculation
Luminescent sensing
Nitroaromatics
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spelling Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic MoleculesPajuelo-Corral, OierRazquin-Bobillo, LauraRojas, SaraGarcía, José A.Choquesillo-Lazarte, DuaneSalinas-Castillo, AlfonsoHernández, RicardoRodríguez-Diéguez, AntonioCepeda, JavierCoordination polymersLanthanide5-methylisophthalatePhotoluminescence propertiesTDDFT calculationsCIS INDO/S calculationsCharge transfers calculationLuminescent sensingNitroaromaticsThe work presented herein reports on the synthesis, structural and physico-chemical characterization, luminescence properties and luminescent sensing activity of a family of isostructural coordination polymers (CPs) with the general formula [Ln(μ-5Meip)(DMF)] (where Ln(III) = Sm (1), Eu (2), Gd (3), Tb (4) and Yb (5) and 5Meip = 5-methylisophthalate, DMF = N,N-dimethylmethanamide). Crystal structures consist of 3D frameworks tailored by the linkage between infinite lanthanide(III)-carboxylate rods by means of the tetradentate 5Meip ligands. Photoluminescence measurements in solid state at variable temperatures reveal the best-in-class properties based on the capacity of the 5Meip ligand to provide efficient energy transfers to the lanthanide(III) ions, which brings intense emissions in both the visible and near-infrared (NIR) regions. On the one hand, compound 5 displays characteristic lanthanide-centered bands in the NIR with sizeable intensity even at room temperature. Among the compounds emitting in the visible region, 4 presents a high QY of 63%, which may be explained according to computational calculations. At last, taking advantage of the good performance as well as high chemical and optical stability of 4 in water and methanol, its sensing capacity to detect 2,4,6-trinitrophenol (TNP) among other nitroaromatic-like explosives has been explored, obtaining high detection capacity (with K around 10 M), low limit of detection (in the 10–10 M) and selectivity among other molecules (especially in methanol).This work has been funded by University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22 and IT1500-22), Junta de Andalucía (FQM-394 and B-FQM-734-UGR20, B-FQM-478-UGR20 and ProyExcel_00386) and the Spanish Ministry of Economy and Competitiveness (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-B-C21 and PID2020-117344RB-I00).Multidisciplinary Digital Publishing InstituteUniversidad del País VascoJunta de AndalucíaMinisterio de Economía y Competitividad (España)Agencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2024202420222024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/357061reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-A-C22info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-B-C21info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-117344RB-I00http://dx.doi.org/10.3390/nano12223977Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3570612026-05-22T06:33:51Z
dc.title.none.fl_str_mv Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
title Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
spellingShingle Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
Pajuelo-Corral, Oier
Coordination polymers
Lanthanide
5-methylisophthalate
Photoluminescence properties
TDDFT calculations
CIS INDO/S calculations
Charge transfers calculation
Luminescent sensing
Nitroaromatics
title_short Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
title_full Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
title_fullStr Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
title_full_unstemmed Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
title_sort Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules
dc.creator.none.fl_str_mv Pajuelo-Corral, Oier
Razquin-Bobillo, Laura
Rojas, Sara
García, José A.
Choquesillo-Lazarte, Duane
Salinas-Castillo, Alfonso
Hernández, Ricardo
Rodríguez-Diéguez, Antonio
Cepeda, Javier
author Pajuelo-Corral, Oier
author_facet Pajuelo-Corral, Oier
Razquin-Bobillo, Laura
Rojas, Sara
García, José A.
Choquesillo-Lazarte, Duane
Salinas-Castillo, Alfonso
Hernández, Ricardo
Rodríguez-Diéguez, Antonio
Cepeda, Javier
author_role author
author2 Razquin-Bobillo, Laura
Rojas, Sara
García, José A.
Choquesillo-Lazarte, Duane
Salinas-Castillo, Alfonso
Hernández, Ricardo
Rodríguez-Diéguez, Antonio
Cepeda, Javier
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad del País Vasco
Junta de Andalucía
Ministerio de Economía y Competitividad (España)
Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Coordination polymers
Lanthanide
5-methylisophthalate
Photoluminescence properties
TDDFT calculations
CIS INDO/S calculations
Charge transfers calculation
Luminescent sensing
Nitroaromatics
topic Coordination polymers
Lanthanide
5-methylisophthalate
Photoluminescence properties
TDDFT calculations
CIS INDO/S calculations
Charge transfers calculation
Luminescent sensing
Nitroaromatics
description The work presented herein reports on the synthesis, structural and physico-chemical characterization, luminescence properties and luminescent sensing activity of a family of isostructural coordination polymers (CPs) with the general formula [Ln(μ-5Meip)(DMF)] (where Ln(III) = Sm (1), Eu (2), Gd (3), Tb (4) and Yb (5) and 5Meip = 5-methylisophthalate, DMF = N,N-dimethylmethanamide). Crystal structures consist of 3D frameworks tailored by the linkage between infinite lanthanide(III)-carboxylate rods by means of the tetradentate 5Meip ligands. Photoluminescence measurements in solid state at variable temperatures reveal the best-in-class properties based on the capacity of the 5Meip ligand to provide efficient energy transfers to the lanthanide(III) ions, which brings intense emissions in both the visible and near-infrared (NIR) regions. On the one hand, compound 5 displays characteristic lanthanide-centered bands in the NIR with sizeable intensity even at room temperature. Among the compounds emitting in the visible region, 4 presents a high QY of 63%, which may be explained according to computational calculations. At last, taking advantage of the good performance as well as high chemical and optical stability of 4 in water and methanol, its sensing capacity to detect 2,4,6-trinitrophenol (TNP) among other nitroaromatic-like explosives has been explored, obtaining high detection capacity (with K around 10 M), low limit of detection (in the 10–10 M) and selectivity among other molecules (especially in methanol).
publishDate 2022
dc.date.none.fl_str_mv 2022
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/357061
url http://hdl.handle.net/10261/357061
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-A-C22
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-B-C21
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-117344RB-I00
http://dx.doi.org/10.3390/nano12223977
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
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