New approach using alternative proteolytic enzymes to the conventional enzyme pronase for the isolation of bread melanoidins

Bread melanoidins are melanoproteins classically extracted with the proteolytic enzyme pronase E (S. griserus). In this study, the structure and functionality of melanoidins extracted with the proteolytic enzymes papain (PE) and enzymes from B. subtillus (SP) and a mixture from B. subtillus and A. o...

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Detalles Bibliográficos
Autores: Cavia Saiz, Mónica, Gerardi, Gisela, Muñiz Rodríguez, Pilar, García Tojal, Javier, Salazar Mardones, Gonzalo
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2025
País:España
Institución:Universidad de Burgos (UBU)
Repositorio:Repositorio Institucional de la Universidad de Burgos (RIUBU)
OAI Identifier:oai:riubu.ubu.es:10259/11151
Acceso en línea:https://hdl.handle.net/10259/11151
Access Level:acceso abierto
Palabra clave:Melanoidins
Proteolytic-enzyme
Structure
Antioxidant
Neurotoxicity
Pan (Alimento)
Alimentos-Análisis
Bread
Food-Analysis
Descripción
Sumario:Bread melanoidins are melanoproteins classically extracted with the proteolytic enzyme pronase E (S. griserus). In this study, the structure and functionality of melanoidins extracted with the proteolytic enzymes papain (PE) and enzymes from B. subtillus (SP) and a mixture from B. subtillus and A. oryzae (MP) were evaluated. PE extracted melanoidins have the highest nitrogen (4.3 %) and protein (29 %) content. FTIR showed that PE had a higher protein content and pronase had higher in carbohydrates. The K420 and K345 values and antioxidant capacities of the PE extract were similar to pronase and higher than the other microbial enzymes. After in vitro digestion, the increased in the antioxidant capacity was most pronounced in the PE extract. No neurotoxicity was observed, as evidenced by no neuronal cell death or changes in neuronal ROS levels. These results indicate that the PE enzyme may be a good alternative to pronase for extraction of melanoidins.