Monolithic CIGS-Perovskite tandem cell for optimal light harvesting without current matching

We present a novel monolithic architecture for optimal light harvesting in multijunction thin film solar cells. In the configuration we consider, formed by a perovskite (PVK) cell overlying a CIGS cell, the current extracted from the two different junctions is decoupled by the insertion of a dielect...

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Detalles Bibliográficos
Autores: Mantilla Perez, Paola, Correa Baena, Juan Pablo, Liu, Quan, Colodrero, Silvia, Toudert, Johann, Saliba, Michale, Hagfeldt, Anders, Martorell Pena, Jordi|||0000-0002-8762-1162
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/112461
Acceso en línea:https://hdl.handle.net/2117/112461
https://dx.doi.org/10.1021/acsphotonics.6b00929
Access Level:acceso abierto
Palabra clave:Solar cells
Photovoltaic power generation
Photonics
CIGS solar cells
Inverse integration
Perovskite solar cells
Serial-parallel configuration
Tandem
Cèl·lules solars
Energia solar fotovoltaica
Fotònica
Àrees temàtiques de la UPC::Física
Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica
Descripción
Sumario:We present a novel monolithic architecture for optimal light harvesting in multijunction thin film solar cells. In the configuration we consider, formed by a perovskite (PVK) cell overlying a CIGS cell, the current extracted from the two different junctions is decoupled by the insertion of a dielectric nonperiodic photonic multilayer structure. This photonic multilayer is designed by an inverse integration approach to confine the incident sunlight above the PVK band gap in the PVK absorber layer, while increasing the transparency for sunlight below the PVK band gap for an efficient coupling into the CIGS bottom cell. To match the maximum power point voltages in a parallel connection of the PVK and CIGS cells, the latter is divided into two subcells by means of a standard three-laser scribing connection. Using realistic parameters for all the layers in the multijunction architecture we predict power conversion efficiencies of 28%. This represents an improvement of 24% and 26% over the best CIGS and PVK single-junction cells, respectively, while at the same time outperforms the corresponding current-matched standard tandem configuration by more than two percentage points.