A comparison of different approaches for the analysis of $^{36}Cl$ in graphite samples

This study compares different approaches for the quantification of the massic activity of $^{36}Cl$ in graphite samples. All approaches consisted of a combustion step in combination with a trapping solution to collect the volatile elements. Two different resins were used to separate $^{36}Cl$ from t...

Descripción completa

Detalles Bibliográficos
Autores: Llopart Babot, Inés, Vasile, M., Dobney, A., Russell, Ben C., Kolmogorova, S., Boden, Sven, Bruggeman, Michel, Leermakers, Martine, Qiao, Jixin, De Souza, V., Tarancón Sanz, Alex, Bagán Navarro, Héctor, Warwick, Phillip E.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2023
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:dnet:recercat____::d1d64454df38bef0ab31c4905cf2b538
Acceso en línea:https://hdl.handle.net/2445/229232
Access Level:acceso abierto
Palabra clave:Piròlisi
Grafit
Química mineralògica
Pyrolysis
Graphite
Mineralogical chemistry
Descripción
Sumario:This study compares different approaches for the quantification of the massic activity of $^{36}Cl$ in graphite samples. All approaches consisted of a combustion step in combination with a trapping solution to collect the volatile elements. Two different resins were used to separate $^{36}Cl$ from the matrix (CL resin and PS resin). Liquid scintillation counting (LSC), scintillation counting (SC) and tandem inductively coupled plasma mass spectrometry (ICP-MS/MS) were used to quantify $^{36}Cl$ activity. The chemical yield in all approaches was determined by means of ion chromatography (IC). In addition, the methods were applied to a real activated graphite sample.