A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate

Anyone can access the published paper FREE OF CHARGE by clicking on this link: [Cualquier persona puede acceder al documento publicado de forma GRATUITA, accediendo a través del enlace]

Bibliographic Details
Authors: Li, Jian, Gao, Zihao Rei, Lin, Qing-Fang, Liu, Chenxu, Gao, Fangxin, Lin, Cong, Zhang, Siyao, Deng, Hua, Mayoral, Álvaro, Fan, Wei, Luo, Song, Chen, Xiaobo, He, Hong, Camblor, Miguel Ángel, Chen, Fei-Jian, Yu, Jihong
Format: article
Status:Versión aceptada para publicación
Publication Date:2023
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/287377
Online Access:http://hdl.handle.net/10261/287377
Access Level:Open access
Keyword:Zeolites
Silicates
id ES_ed0ef0a308abba9255b8a005edbb243f
oai_identifier_str oai:digital.csic.es:10261/287377
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
title A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
spellingShingle A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
Li, Jian
Zeolites
Silicates
title_short A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
title_full A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
title_fullStr A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
title_full_unstemmed A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
title_sort A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicate
dc.creator.none.fl_str_mv Li, Jian
Gao, Zihao Rei
Lin, Qing-Fang
Liu, Chenxu
Gao, Fangxin
Lin, Cong
Zhang, Siyao
Deng, Hua
Mayoral, Álvaro
Fan, Wei
Luo, Song
Chen, Xiaobo
He, Hong
Camblor, Miguel Ángel
Chen, Fei-Jian
Yu, Jihong
author Li, Jian
author_facet Li, Jian
Gao, Zihao Rei
Lin, Qing-Fang
Liu, Chenxu
Gao, Fangxin
Lin, Cong
Zhang, Siyao
Deng, Hua
Mayoral, Álvaro
Fan, Wei
Luo, Song
Chen, Xiaobo
He, Hong
Camblor, Miguel Ángel
Chen, Fei-Jian
Yu, Jihong
author_role author
author2 Gao, Zihao Rei
Lin, Qing-Fang
Liu, Chenxu
Gao, Fangxin
Lin, Cong
Zhang, Siyao
Deng, Hua
Mayoral, Álvaro
Fan, Wei
Luo, Song
Chen, Xiaobo
He, Hong
Camblor, Miguel Ángel
Chen, Fei-Jian
Yu, Jihong
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv National Natural Science Foundation of China
National Key Research and Development Program (China)
Anhui Province
Ministerio de Ciencia e Innovación (España)
Knut and Alice Wallenberg Foundation
European Commission
Department of Energy (US)
Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
Diputación General de Aragón
Gobierno de Aragón
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Zeolites
Silicates
topic Zeolites
Silicates
description Anyone can access the published paper FREE OF CHARGE by clicking on this link: [Cualquier persona puede acceder al documento publicado de forma GRATUITA, accediendo a través del enlace]
publishDate 2023
dc.date.none.fl_str_mv 2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/287377
url http://hdl.handle.net/10261/287377
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105479RB-I00
info:eu-repo/grantAgreement//EC/H2020
info:eu-repo/grantAgreement/AEI//RYC2018-024561-I
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1126/science.ade1771
https://www.science.org/stoken/author-tokens/ST-242/full
https://www.science.org/doi/epdf/10.1126/science.ade1771
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling A 3D extra-large-pore zeolite enabled by 1D-to-3Dtopotactic condensation of a chain silicateLi, JianGao, Zihao ReiLin, Qing-FangLiu, ChenxuGao, FangxinLin, CongZhang, SiyaoDeng, HuaMayoral, ÁlvaroFan, WeiLuo, SongChen, XiaoboHe, HongCamblor, Miguel ÁngelChen, Fei-JianYu, JihongZeolitesSilicatesAnyone can access the published paper FREE OF CHARGE by clicking on this link: [Cualquier persona puede acceder al documento publicado de forma GRATUITA, accediendo a través del enlace]Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cationexchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption andprocessing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silicazeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open throughwindows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolitewas formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensationof a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed ahigh performance for volatile organic compound abatement and recovery compared with other zeolites andmetal-organic frameworks.This work was supportedby the his work was supportedby the National Natural Science Foundation of China (grants 22288101, 21920102005, 21835002, 22271115, 21601004,21621001, 21776312, and 22078364), the National Key Researchand Development Program of China (grants 2022YFA1503600 and2021YFA1501202), the 111 Project (grant B17020), the Natural Science Foundation of the Higher Education Institutions of Anhui Province, China (grant KJ2020A0585), and the Spanish Ministry of Science Innovation (grants PID2019-105479RB-I00 project,MCIN/AEI/10.13039/501100011033, and RYC2018-024561-I). ThecRED data were collected at the Electron Microscopy Center (EMC), Department of Materials and Environmental Chemistry(MMK), at Stockholm University with the support of the Knut and Alice Wallenberg Foundation (KAW, 2012-0112) through the 3DEM-NATUR project. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the US Departmentof Energy, Office of Science, Office of Basic Energy Sciences,under contract no. DE-AC02-06CH11357. Additional funding fromthe European Union’s Horizon 2020 research and innovationprogram (grant 823717-ESTEEM3) and the regional governmentof Aragon (grant DGA E13_20R) is also acknowledged.(grants22288101, 21920102005, 21835002, 22271115, 21601004,21621001, 21776312, and 22078364), the National Key Researchand Development Program of China (grants 2022YFA1503600 and2021YFA1501202), the 111 Project (grant B17020), the NaturalScience Foundation of the Higher Education Institutions of AnhuiProvince, China (grant KJ2020A0585), and the Spanish Ministryof Science Innovation (grants PID2019-105479RB-I00 project,MCIN/AEI/10.13039/501100011033, and RYC2018-024561-I). ThecRED data were collected at the Electron Microscopy Center(EMC), Department of Materials and Environmental Chemistry(MMK), at Stockholm University with the support of the Knut andAlice Wallenberg Foundation (KAW, 2012-0112) through the3DEM-NATUR project. Use of the Advanced Photon Source atArgonne National Laboratory was supported by the US Departmentof Energy, Office of Science, Office of Basic Energy Sciences,under contract no. DE-AC02-06CH11357. Additional funding fromthe European Union’s Horizon 2020 research and innovationprogram (grant 823717-ESTEEM3) and the regional governmentof Aragon (grant DGA E13_20R) is also acknowledged.Peer reviewedNational Natural Science Foundation of ChinaNational Key Research and Development Program (China)Anhui ProvinceMinisterio de Ciencia e Innovación (España)Knut and Alice Wallenberg FoundationEuropean CommissionDepartment of Energy (US)Ministerio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)Diputación General de AragónGobierno de AragónConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202320232023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10261/287377reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105479RB-I00info:eu-repo/grantAgreement//EC/H2020info:eu-repo/grantAgreement/AEI//RYC2018-024561-IThe underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1126/science.ade1771https://www.science.org/stoken/author-tokens/ST-242/fullhttps://www.science.org/doi/epdf/10.1126/science.ade1771Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2873772026-05-22T06:33:51Z
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