Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments

Radishes are rich in health-promoting organosulfur compounds. This study investigated the effects of gastrointestinal digestion (GID) on glucosinolates (GSLs) and isothiocyanates (ITCs) of two radish microgreens cultivars (Raphanus sativus; cv. Daikon, and cv. Red Rambo) grown in a closed vertical s...

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Autores: Silva, Marta, Domínguez-Perles, Raúl, Moreno, Diego A., Viegas, Olga, Faria, Miguel A., Carvalho, Susana M. P., Ferreira, Isabel M. P. L. V. O.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/397177
Acceso en línea:http://hdl.handle.net/10261/397177
https://api.elsevier.com/content/abstract/scopus_id/105008503373
Access Level:acceso abierto
Palabra clave:Glucosinolates
Isothiocyanates
INFOGEST
Growing lights
Structural equation modelling
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spelling Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatmentsSilva, MartaDomínguez-Perles, RaúlMoreno, Diego A.Viegas, OlgaFaria, Miguel A.Carvalho, Susana M. P.Ferreira, Isabel M. P. L. V. O.GlucosinolatesIsothiocyanatesINFOGESTGrowing lightsStructural equation modellingRadishes are rich in health-promoting organosulfur compounds. This study investigated the effects of gastrointestinal digestion (GID) on glucosinolates (GSLs) and isothiocyanates (ITCs) of two radish microgreens cultivars (Raphanus sativus; cv. Daikon, and cv. Red Rambo) grown in a closed vertical system under either White (W) or Red+Blue (R + B) LEDs, combined with varying applications of UV-C radiation (0, 1, or 3 pulses). The individual and combined effects of LEDs and UV-C on GSLs and ITCs were evaluated before and after GID (INFOGEST static in vitro GID model). Relationships between compounds before/after digestion were explored through Structural Equation Modelling (SEM). Both cultivars are good sources of aliphatic GSLs (Daikon: 513.4 ± 23.1-681.5 ± 31.9, Red Rambo: 447.5 ± 38.5-532.0 ± 20.2 mg 100 g-1) and ITCs (Daikon: 0.9 ± 0.1-1.8 ± 0.3, Red Rambo: 1.3 ± 0.2-5.2 ± 1.0 mg 100 g-1). LED type was more impactful than UV-C radiation. Generally, R + B LEDs enhanced GSLs due to increasing dehydroerucin in Daikon, while improving ITCs in Red Rambo. Post-digestion, Red Rambo showed markedly higher sulforaphene levels compared to Daikon. Red Rambo's SEM significantly confirmed the conversion of glucoraphenin into sulforaphene and sulforaphane during GID. In Daikon, no significant relationships between compounds before/after GID were found. These findings suggest cultivar-specific metabolic pathways and responses to light, which can be optimized to enhance the accumulation of health-related compounds. The innovative use of SEM provided deeper insights into the metabolic conversions occurring during GID. The abundant sulforaphene levels from Red Rambo highlight this cultivar as an excellent source of this metabolite and its potential health benefitsThis work was supported through the strategic projects (UIDB/50006/2020, UIDP/50006/2020, UIDB/05748/2020, UIDP/05748/2020) funded by FCT/MCTES through national funds, and the R&D projects SALIVA+ (2022.08978.PTDC) and SNAP I&D (NORTE-01-0145-FEDER-000085). Marta Silva wishes to thank FCT for the Ph.D. Grant (10.54499/2020.05266.BD). M. A. Faria thanks FCT the researcher contract CEECINSTLA/00029/2022. D.A.M. would also like to express his gratitude to HORTNEX project that partially funded this research, under the AGROALNEXT (Agroalnext_2022_027) programme of MCIN and funded by the European Union “NextGenerationEU” (PRTR-C17·I1) and by the Generalitat ValencianaPeer reviewedElsevierFundação para a Ciência e a Tecnologia (Portugal)European CommissionGeneralitat ValencianaMinisterio de Ciencia e Innovación (España)Domínguez-Perles, Raúl [0000-0001-6232-712X]Moreno, Diego A. [0000-0002-6547-8764]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252025info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/397177https://api.elsevier.com/content/abstract/scopus_id/105008503373reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésFood research international (Ottawa, Ont.)The underlying dataset has been published as supplementary material of the article in the publisher platform at https://doi.org/10.1016/j.foodres.2025.116831https://doi.org/10.1016/j.foodres.2025.116831Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3971772026-05-22T06:33:51Z
dc.title.none.fl_str_mv Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
title Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
spellingShingle Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
Silva, Marta
Glucosinolates
Isothiocyanates
INFOGEST
Growing lights
Structural equation modelling
title_short Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
title_full Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
title_fullStr Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
title_full_unstemmed Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
title_sort Digestion of organosulfur compounds of two radish microgreen cultivars grown under different light treatments
dc.creator.none.fl_str_mv Silva, Marta
Domínguez-Perles, Raúl
Moreno, Diego A.
Viegas, Olga
Faria, Miguel A.
Carvalho, Susana M. P.
Ferreira, Isabel M. P. L. V. O.
author Silva, Marta
author_facet Silva, Marta
Domínguez-Perles, Raúl
Moreno, Diego A.
Viegas, Olga
Faria, Miguel A.
Carvalho, Susana M. P.
Ferreira, Isabel M. P. L. V. O.
author_role author
author2 Domínguez-Perles, Raúl
Moreno, Diego A.
Viegas, Olga
Faria, Miguel A.
Carvalho, Susana M. P.
Ferreira, Isabel M. P. L. V. O.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Fundação para a Ciência e a Tecnologia (Portugal)
European Commission
Generalitat Valenciana
Ministerio de Ciencia e Innovación (España)
Domínguez-Perles, Raúl [0000-0001-6232-712X]
Moreno, Diego A. [0000-0002-6547-8764]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Glucosinolates
Isothiocyanates
INFOGEST
Growing lights
Structural equation modelling
topic Glucosinolates
Isothiocyanates
INFOGEST
Growing lights
Structural equation modelling
description Radishes are rich in health-promoting organosulfur compounds. This study investigated the effects of gastrointestinal digestion (GID) on glucosinolates (GSLs) and isothiocyanates (ITCs) of two radish microgreens cultivars (Raphanus sativus; cv. Daikon, and cv. Red Rambo) grown in a closed vertical system under either White (W) or Red+Blue (R + B) LEDs, combined with varying applications of UV-C radiation (0, 1, or 3 pulses). The individual and combined effects of LEDs and UV-C on GSLs and ITCs were evaluated before and after GID (INFOGEST static in vitro GID model). Relationships between compounds before/after digestion were explored through Structural Equation Modelling (SEM). Both cultivars are good sources of aliphatic GSLs (Daikon: 513.4 ± 23.1-681.5 ± 31.9, Red Rambo: 447.5 ± 38.5-532.0 ± 20.2 mg 100 g-1) and ITCs (Daikon: 0.9 ± 0.1-1.8 ± 0.3, Red Rambo: 1.3 ± 0.2-5.2 ± 1.0 mg 100 g-1). LED type was more impactful than UV-C radiation. Generally, R + B LEDs enhanced GSLs due to increasing dehydroerucin in Daikon, while improving ITCs in Red Rambo. Post-digestion, Red Rambo showed markedly higher sulforaphene levels compared to Daikon. Red Rambo's SEM significantly confirmed the conversion of glucoraphenin into sulforaphene and sulforaphane during GID. In Daikon, no significant relationships between compounds before/after GID were found. These findings suggest cultivar-specific metabolic pathways and responses to light, which can be optimized to enhance the accumulation of health-related compounds. The innovative use of SEM provided deeper insights into the metabolic conversions occurring during GID. The abundant sulforaphene levels from Red Rambo highlight this cultivar as an excellent source of this metabolite and its potential health benefits
publishDate 2025
dc.date.none.fl_str_mv 2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/397177
https://api.elsevier.com/content/abstract/scopus_id/105008503373
url http://hdl.handle.net/10261/397177
https://api.elsevier.com/content/abstract/scopus_id/105008503373
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Food research international (Ottawa, Ont.)
The underlying dataset has been published as supplementary material of the article in the publisher platform at https://doi.org/10.1016/j.foodres.2025.116831
https://doi.org/10.1016/j.foodres.2025.116831

dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
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