Microwave-assisted production of furfural from the hemicellulosic fraction of olive stones

Olive stone (OS) is a lignocellulosic material obtained as a coproduct in the olive oil production industry, mainly composed of hemicelluloses, with xylose accounting for 24.4% by weight as the main sugar. In this study, an optimized process for obtaining furfural from OS was assessed. The process c...

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Detalles Bibliográficos
Autores: Ruiz, Encarnación, Padilla-Rascón, Carmen, Romero-García, Juan Miguel, Romero, Inmaculada, Castro, Eulogio
Tipo de recurso: artículo
Estado:Versión borrador
Fecha de publicación:2021
País:España
Institución:Universidad de Jaén
Repositorio:RUJA. Repositorio Institucional de la Producción Científica de la Universidad de Jaén
OAI Identifier:oai:ruja.ujaen.es:10953/7174
Acceso en línea:https://doi.org/10.1016/j.psep.2021.06.035
https://hdl.handle.net/10953/7174
Access Level:acceso abierto
Palabra clave:Olive biomass
xylose
furfural
microwave
Optimization
6: Ciencias aplicadas. Medicina. Tecnología
Descripción
Sumario:Olive stone (OS) is a lignocellulosic material obtained as a coproduct in the olive oil production industry, mainly composed of hemicelluloses, with xylose accounting for 24.4% by weight as the main sugar. In this study, an optimized process for obtaining furfural from OS was assessed. The process consists of two steps; the first one, aimed at maximizing the solubilization of xylose, was performed in an autoclave at 130ºC and 2.6 %w/v H2SO4, resulting in 83% xylose recovery in the liquid fraction. The second step, using the optimized liquid produced previously, was carried out in a microwave reactor at 200 ºC with the addition of 0.1 M FeCl3 from which a solution with 18 g/L furfural and 63.3% yield was obtained, equivalent to almost 90 kg of furfural per tonne of processed OS. As a conclusion, this underutilized lignocellulosic material can be considered as a promising renewable source of furfural.