Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities

Ulva rigida seaweed is constituted by ulvan, which is a sulfated polysaccharide with uses in a wide variety of applications. After the ulvan-oriented extraction process, a crystalline and recalcitrant residue, the so-called pulp, appears. In this work, this residue was valorized through a multiple-s...

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Authors: Llano Astuy, Tamara|||0000-0003-4982-0918, Arce Gutiérrez, Carlos, Gallart Tauler, Lien Ester, Perales García, Ana, Coz Fernández, Alberto|||0000-0002-0453-4769
Format: article
Publication Date:2023
Country:España
Institution:Universidad de Cantabria (UC)
Repository:UCrea Repositorio Abierto de la Universidad de Cantabria
Language:English
OAI Identifier:oai:repositorio.unican.es:10902/28729
Online Access:https://hdl.handle.net/10902/28729
Access Level:Open access
Keyword:ABE fermentation
Bioethanol
Butanol
Modelling
Seaweed
Ulva rigida
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spelling Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilitiesLlano Astuy, Tamara|||0000-0003-4982-0918Arce Gutiérrez, CarlosGallart Tauler, Lien EsterPerales García, AnaCoz Fernández, Alberto|||0000-0002-0453-4769ABE fermentationBioethanolButanolModellingSeaweedUlva rigidaUlva rigida seaweed is constituted by ulvan, which is a sulfated polysaccharide with uses in a wide variety of applications. After the ulvan-oriented extraction process, a crystalline and recalcitrant residue, the so-called pulp, appears. In this work, this residue was valorized through a multiple-stage process. The total processing of the algae consists of hot water extraction, acid hydrolysis, ABE fermentation, and distillation in order to obtain not only ulvan but also butanol and bioethanol to be used as biofuels by simulating two third-generation algae-based biorefineries in Aspen Plus v10 software. Third-generation plants do not compete with food and algae biomass, and they do not require delignification nor pretreatment steps, which are usually the bottleneck of second-generation plants. A plant producing butanol as biofuel together with diluted ulvan, acetone, and ethanol as byproducts was modelled in Aspen Plus software. Regarding the profitability of the investment, the plants producing bioethanol and butanol were economically feasible. The economic parameters for the bioethanol and butanol plants were as follows: NPV equal to 27.66 M$ and 16.67 M$, and IRR equal to 46% and 37%, respectively. The discounted return period was acceptable for these types of plants, which were 4.11 and 3.16 years for the ABE biorefinery and the bioethanol biorefinery, respectively.This research was funded by EUROPEAN COMMISSION, Marie Sklodowska-Curie Actions-RISE, grant number 101007733 (CELISE project https://celise.unican.es/), and by AHTI INVESTALGA S.L. company under projects CIRCULVA and POLIEXTRALGA.MDPIUniversidad de Cantabria20232023-03-29journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articlehttps://hdl.handle.net/10902/28729Fermentation, 2023, 9(4), 340reponame:UCrea Repositorio Abierto de la Universidad de Cantabriainstname:Universidad de Cantabria (UC)InglésengEuropean Commission http://dx.doi.org/10.13039/501100000780 Horizon 2020 Framework Programme 101007733open accesshttp://purl.org/coar/access_right/c_abf2Attribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:repositorio.unican.es:10902/287292026-06-02T12:39:31Z
dc.title.none.fl_str_mv Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
title Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
spellingShingle Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
Llano Astuy, Tamara|||0000-0003-4982-0918
ABE fermentation
Bioethanol
Butanol
Modelling
Seaweed
Ulva rigida
title_short Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
title_full Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
title_fullStr Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
title_full_unstemmed Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
title_sort Techno-economic analysis of macroalgae biorefineries: a comparison between ethanol and butanol facilities
dc.creator.none.fl_str_mv Llano Astuy, Tamara|||0000-0003-4982-0918
Arce Gutiérrez, Carlos
Gallart Tauler, Lien Ester
Perales García, Ana
Coz Fernández, Alberto|||0000-0002-0453-4769
author Llano Astuy, Tamara|||0000-0003-4982-0918
author_facet Llano Astuy, Tamara|||0000-0003-4982-0918
Arce Gutiérrez, Carlos
Gallart Tauler, Lien Ester
Perales García, Ana
Coz Fernández, Alberto|||0000-0002-0453-4769
author_role author
author2 Arce Gutiérrez, Carlos
Gallart Tauler, Lien Ester
Perales García, Ana
Coz Fernández, Alberto|||0000-0002-0453-4769
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidad de Cantabria
dc.subject.none.fl_str_mv ABE fermentation
Bioethanol
Butanol
Modelling
Seaweed
Ulva rigida
topic ABE fermentation
Bioethanol
Butanol
Modelling
Seaweed
Ulva rigida
description Ulva rigida seaweed is constituted by ulvan, which is a sulfated polysaccharide with uses in a wide variety of applications. After the ulvan-oriented extraction process, a crystalline and recalcitrant residue, the so-called pulp, appears. In this work, this residue was valorized through a multiple-stage process. The total processing of the algae consists of hot water extraction, acid hydrolysis, ABE fermentation, and distillation in order to obtain not only ulvan but also butanol and bioethanol to be used as biofuels by simulating two third-generation algae-based biorefineries in Aspen Plus v10 software. Third-generation plants do not compete with food and algae biomass, and they do not require delignification nor pretreatment steps, which are usually the bottleneck of second-generation plants. A plant producing butanol as biofuel together with diluted ulvan, acetone, and ethanol as byproducts was modelled in Aspen Plus software. Regarding the profitability of the investment, the plants producing bioethanol and butanol were economically feasible. The economic parameters for the bioethanol and butanol plants were as follows: NPV equal to 27.66 M$ and 16.67 M$, and IRR equal to 46% and 37%, respectively. The discounted return period was acceptable for these types of plants, which were 4.11 and 3.16 years for the ABE biorefinery and the bioethanol biorefinery, respectively.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-03-29
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10902/28729
url https://hdl.handle.net/10902/28729
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission http://dx.doi.org/10.13039/501100000780 Horizon 2020 Framework Programme 101007733
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv Fermentation, 2023, 9(4), 340
reponame:UCrea Repositorio Abierto de la Universidad de Cantabria
instname:Universidad de Cantabria (UC)
instname_str Universidad de Cantabria (UC)
reponame_str UCrea Repositorio Abierto de la Universidad de Cantabria
collection UCrea Repositorio Abierto de la Universidad de Cantabria
repository.name.fl_str_mv
repository.mail.fl_str_mv
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