Switchable Surface Hydrophobicity-Hydrophilicity of a Metal-Organic Framework

Materials with surfaces that can be switched from high/superhydrophobicity to superhydrophilicity are useful for myriad applications. Herein, we report a metal-organic framework (MOF) assembled from Znions, 1,4-benzenedicarboxylate, and a hydrophobic carborane-based linker. The MOF crystal-surface c...

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Detalles Bibliográficos
Autores: Rodríguez-Hermida, Sabina|||0000-0001-7671-9925, Ying Tsang, Min, Vignatti Abellan, Claudia|||0000-0003-3462-0251, Stylianou, Kyriakos C.|||0000-0003-1670-0020, Guillerm, Vincent|||0000-0003-3460-223X, Pérez-Carvajal, Javier|||0000-0002-6916-1158, Teixidor, Francesc|||0000-0002-3010-2417, Viñas, Clara|||0000-0001-5000-0277, Choquesillo-Lazarte, Duane|||0000-0002-7077-8972, Verdugo-Escamilla, Cristóbal|||0000-0003-2345-8359, Peral Alonso, Inmaculada|||0000-0002-6994-1277, Juanhuix, Judith|||0000-0003-3728-8215, Verdaguer Prats, Albert|||0000-0002-4855-821X, Imaz, Inhar|||0000-0002-0278-1141, Maspoch Comamala, Daniel|||0000-0003-1325-9161, Giner Planas, José|||0000-0002-1648-2169
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:216230
Acceso en línea:https://ddd.uab.cat/record/216230
https://dx.doi.org/urn:doi:10.1002/anie.201609295
Access Level:acceso abierto
Palabra clave:Carboranes
Hydrophilicity
Hydrophobicity
Metal-organic frameworks
Surface chemistry
Descripción
Sumario:Materials with surfaces that can be switched from high/superhydrophobicity to superhydrophilicity are useful for myriad applications. Herein, we report a metal-organic framework (MOF) assembled from Znions, 1,4-benzenedicarboxylate, and a hydrophobic carborane-based linker. The MOF crystal-surface can be switched between hydrophobic and superhydrophilic through a chemical treatment to remove some of the building blocks.

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