Diarylplatinum(II) compounds as versatile metallating agents in the synthesis of cyclometallated platinum compounds with N-donor ligands
This review deals with the reactions of diarylplatinum(II) complexes with N-donor ligands to produce a variety of cycloplatinated compounds including endo-five-, endo-seven-, endo-six- or exo-five-membered platinacycles. The observed reactions result from a series of oxidative addition/reductive eli...
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2014 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/137097 |
| Acceso en línea: | https://hdl.handle.net/2445/137097 |
| Access Level: | acceso abierto |
| Palabra clave: | Platí Lligands Platinum Ligands |
| Sumario: | This review deals with the reactions of diarylplatinum(II) complexes with N-donor ligands to produce a variety of cycloplatinated compounds including endo-five-, endo-seven-, endo-six- or exo-five-membered platinacycles. The observed reactions result from a series of oxidative addition/reductive elimination processes taking place at platinum(II)/platinum(IV) species and involving C-X (X = H, Cl, Br) bond activation, arene elimination, and, in some cases, Caryl-Caryl bond formation. |
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