Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method

Supported liquid membranes (SLMs) containing novel green solvents are proposed as a sustainable alternative separation process in the recovery of biomolecules. In this work, succinic acid has been successfully extracted from model fermentation broths through a stripping phase-facilitated transport m...

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Detalles Bibliográficos
Autores: López-Porfiri, Pablo, González-Miquel, María, Gorgojo, Patricia
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/280326
Acceso en línea:http://hdl.handle.net/10261/280326
Access Level:acceso abierto
Palabra clave:Supported liquid membrane (SLMs)
Green solvent
Organic acid
Biorefinery
Process design
COSMO-RS
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spelling Green supported liquid membranes: The permeability activity-based linear operation (PABLO) methodLópez-Porfiri, PabloGonzález-Miquel, MaríaGorgojo, PatriciaSupported liquid membrane (SLMs)Green solventOrganic acidBiorefineryProcess designCOSMO-RSSupported liquid membranes (SLMs) containing novel green solvents are proposed as a sustainable alternative separation process in the recovery of biomolecules. In this work, succinic acid has been successfully extracted from model fermentation broths through a stripping phase-facilitated transport mechanism with four different green supported liquid membranes: two eutectic solvents (DL-menthol:OctA and N4444Cl:OctA), the bio-based solvent eucalyptol and the ionic liquid [C4pyrr][Tf2N]. A permeability activity-based model that takes into account for the first time solute-phase affinities has been developed using the quantum chemical COSMO-RS method; the model corrects the mass transfer driving force and allows extraction predictions beyond the concentration equilibrium. The best recovery has been achieved experimentally for the eucalyptol-based SLM (concentration factor of 1.4) using an alkaline aqueous solution (0.5 M NaOH) as the stripping phase. A countercurrent cascade extraction process design is proposed, and a graphical method to determine the stage number, interstage concentrations as well as mass transfer area requirements is presented. This new tool, the Permeability Activity-Based Linear Operation (PABLO) method, will substantially enhance the process design of SLMs technology for the biorefinery industry.This work was funded by the CONICYT PFCHA/DOCTORADO BECAS CHILE/2017 – 72180306. P. Gorgojo acknowledges the Spanish Ministry of Economy and Competitiveness and the European Social Fund through the Ramon y Cajal programme (RYC2019-027060-I/AEI/10.13039/501100011033). M. González-Miquel acknowledges Madrid Government (Comunidad de Madrid-Spain) for funding through the Multiannual Agreement with Universidad Politécnica de Madrid under the Excellence Programme for University Professors, in the context of the V PRICIT (Regional Programme of Research and Technological Innovation).Peer reviewedElsevierComisión Nacional de Investigación Científica y Tecnológica (Chile)Agencia Estatal de Investigación (España)Ministerio de Ciencia, Innovación y Universidades (España)Ministerio de Economía y Competitividad (España)Comunidad de MadridUniversidad Politécnica de MadridConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202220222022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/280326reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI//RYC2019-027060-Ihttps://doi.org/10.1016/j.cej.2022.137253Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2803262026-05-22T06:33:51Z
dc.title.none.fl_str_mv Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
title Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
spellingShingle Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
López-Porfiri, Pablo
Supported liquid membrane (SLMs)
Green solvent
Organic acid
Biorefinery
Process design
COSMO-RS
title_short Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
title_full Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
title_fullStr Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
title_full_unstemmed Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
title_sort Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
dc.creator.none.fl_str_mv López-Porfiri, Pablo
González-Miquel, María
Gorgojo, Patricia
author López-Porfiri, Pablo
author_facet López-Porfiri, Pablo
González-Miquel, María
Gorgojo, Patricia
author_role author
author2 González-Miquel, María
Gorgojo, Patricia
author2_role author
author
dc.contributor.none.fl_str_mv Comisión Nacional de Investigación Científica y Tecnológica (Chile)
Agencia Estatal de Investigación (España)
Ministerio de Ciencia, Innovación y Universidades (España)
Ministerio de Economía y Competitividad (España)
Comunidad de Madrid
Universidad Politécnica de Madrid
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Supported liquid membrane (SLMs)
Green solvent
Organic acid
Biorefinery
Process design
COSMO-RS
topic Supported liquid membrane (SLMs)
Green solvent
Organic acid
Biorefinery
Process design
COSMO-RS
description Supported liquid membranes (SLMs) containing novel green solvents are proposed as a sustainable alternative separation process in the recovery of biomolecules. In this work, succinic acid has been successfully extracted from model fermentation broths through a stripping phase-facilitated transport mechanism with four different green supported liquid membranes: two eutectic solvents (DL-menthol:OctA and N4444Cl:OctA), the bio-based solvent eucalyptol and the ionic liquid [C4pyrr][Tf2N]. A permeability activity-based model that takes into account for the first time solute-phase affinities has been developed using the quantum chemical COSMO-RS method; the model corrects the mass transfer driving force and allows extraction predictions beyond the concentration equilibrium. The best recovery has been achieved experimentally for the eucalyptol-based SLM (concentration factor of 1.4) using an alkaline aqueous solution (0.5 M NaOH) as the stripping phase. A countercurrent cascade extraction process design is proposed, and a graphical method to determine the stage number, interstage concentrations as well as mass transfer area requirements is presented. This new tool, the Permeability Activity-Based Linear Operation (PABLO) method, will substantially enhance the process design of SLMs technology for the biorefinery industry.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/280326
url http://hdl.handle.net/10261/280326
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI//RYC2019-027060-I
https://doi.org/10.1016/j.cej.2022.137253
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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