Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead

Producción Científica

Detalhes bibliográficos
Autores: Waters, Jessica E., Berger, Georg, Peel, Andrew J., García Rodríguez, Raúl, Bond, Andrew D., Wright, Dominic Simon
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Recursos:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/49359
Acesso em linha:https://doi.org/10.1002/chem.202101291
https://uvadoc.uva.es/handle/10324/49359
Access Level:acceso abierto
Palavra-chave:Coordination networks
Redes de coordinación
Pnictogens
Pnictógeno
Tripodal ligands
Ligandos tripodales
Topology
Topología
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spelling Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgeheadWaters, Jessica E.Berger, GeorgPeel, Andrew J.García Rodríguez, RaúlBond, Andrew D.Wright, Dominic SimonCoordination networksRedes de coordinaciónPnictogensPnictógenoTripodal ligandsLigandos tripodalesTopologyTopologíaProducción CientíficaSupramolecular main group chemistry is a developing field which parallels the conventional domain of metallo-organic chemistry. Little explored building blocks in this area are main group metal-based ligands which have the appropriate donor symmetry to build desired molecular or extended arrangements. Tris(pyridyl) main group ligands (E(py)3, E=main group metal) are potentially highly versatile building blocks since shifting the N-donor arms from the 2- to the 3-positions and 4-positions provides a very simple way of changing the ligand character from mononuclear/chelating to multidentate/metal-bridging. Here, the coordination behaviour of the first main group metal tris(4-pyridyl) ligands, E(4-py)3 (E=Sb, Bi, Ph−Sn) is explored, as well as their ability to build metal-organic frameworks (MOFs). The complicated topology of these MOFs shows a marked influence on the counter anion and on the ability of the E(4-py)3 ligands to switch coordination mode, depending on the steric and donor character of the bridgehead. This structure-directing influence of the bridgehead provides a potential building strategy for future molecular and MOF design in this area.Leverhulme Trust (grant RPG-2017-146)Ministerio de Economía, Industria y Competitividad - Agencia Estatal de Investigación - Fondo Social Europeo (contract RYC-2015-19035)Ministerio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación - Fondo Europeo de Desarrollo Regional (grant PGC2018-096880-A-I00)Wiley2021info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://doi.org/10.1002/chem.202101291https://uvadoc.uva.es/handle/10324/49359reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202101291info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/oai:uvadoc.uva.es:10324/493592026-06-13T12:44:47Z
dc.title.none.fl_str_mv Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
title Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
spellingShingle Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
Waters, Jessica E.
Coordination networks
Redes de coordinación
Pnictogens
Pnictógeno
Tripodal ligands
Ligandos tripodales
Topology
Topología
title_short Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
title_full Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
title_fullStr Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
title_full_unstemmed Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
title_sort Uncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgehead
dc.creator.none.fl_str_mv Waters, Jessica E.
Berger, Georg
Peel, Andrew J.
García Rodríguez, Raúl
Bond, Andrew D.
Wright, Dominic Simon
author Waters, Jessica E.
author_facet Waters, Jessica E.
Berger, Georg
Peel, Andrew J.
García Rodríguez, Raúl
Bond, Andrew D.
Wright, Dominic Simon
author_role author
author2 Berger, Georg
Peel, Andrew J.
García Rodríguez, Raúl
Bond, Andrew D.
Wright, Dominic Simon
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Coordination networks
Redes de coordinación
Pnictogens
Pnictógeno
Tripodal ligands
Ligandos tripodales
Topology
Topología
topic Coordination networks
Redes de coordinación
Pnictogens
Pnictógeno
Tripodal ligands
Ligandos tripodales
Topology
Topología
description Producción Científica
publishDate 2021
dc.date.none.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1002/chem.202101291
https://uvadoc.uva.es/handle/10324/49359
url https://doi.org/10.1002/chem.202101291
https://uvadoc.uva.es/handle/10324/49359
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202101291
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.301603

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