The role of the electric conductivity of carbons in the electrochemical capacitor performance
The interpretation of the performance of electrochemical capacitors based exclusively on the textural features and surface chemistry of carbons can be insufficient, or even misleading, in the case of materials prepared at low temperatures (typically below 800 °C). It is suggested that the gradual im...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2011 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/100226 |
| Acceso en línea: | http://hdl.handle.net/10261/100226 |
| Access Level: | acceso abierto |
| Palabra clave: | Activated carbon Heat-treatment Electric conductivity Electrochemical capacitor |
| Sumario: | The interpretation of the performance of electrochemical capacitors based exclusively on the textural features and surface chemistry of carbons can be insufficient, or even misleading, in the case of materials prepared at low temperatures (typically below 800 °C). It is suggested that the gradual improvement of the electrochemical performances of carbon-based capacitors at high current densities, following heat treatments up to 900 °C, is mainly a consequence of the simultaneous increase in conductivity. This is illustrated by a study of carbons based on a mesoporous carbon prepared at 550 °C, which displays poor electrochemical performances and a low conductivity (4.6 × 10−6 S m−1). A first heat treatment at 700 °C leads to major structural, chemical and electrochemical changes, due to the collapse of the smaller mesopores and the formation of a microporous structure with average pore widths around 1.3 nm. One also observes a reduction in the surface oxygen density from 13 to approximately 5 μmol m−2. Further heat treatments at 800 and 900 °C do not modify significantly these characteristics, nor the surface-related capacitances at low current densities (1 mA cm−2) in the aqueous (2 M H2SO4) and organic (1 M (C2H5)4NBF4/CH3CN) electrolytes. On the other hand, one observes increasingly high rate capabilities which may be ascribed to the simultaneous increase in conductivity from 7.3 to 147.8 S m−1 between 700 and 900 °C. |
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