Vibration and two-photon absorption

The rigorous and transparent treatment of the effects of nuclear vibrational motion in two-photon absorption (TPA) was discussed. Perturbation formula for diatomic molecules were developed and applied to the X¹Σ+–A¹Π transition in CO. The analysis showed that the vibrations played an important role...

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Detalles Bibliográficos
Autores: Bishop, David M., Luis Luis, Josep Maria, Kirtman, Bernard
Tipo de recurso: artículo
Fecha de publicación:2002
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/3193
Acceso en línea:http://hdl.handle.net/10256/3193
Access Level:acceso abierto
Palabra clave:Absorció de la llum
Col·lisions (Física nuclear)
Fotons
Collisions (Nuclear physics)
Light absorption
Photons
Descripción
Sumario:The rigorous and transparent treatment of the effects of nuclear vibrational motion in two-photon absorption (TPA) was discussed. Perturbation formula for diatomic molecules were developed and applied to the X¹Σ+–A¹Π transition in CO. The analysis showed that the vibrations played an important role in TPA, just as their role in the calculation of conventional nonlinear optical (NLO) hyperpolarizabilities